Fe-MOF derivative photocatalyst with advanced oxygen reduction capacity for indoor pollutants removal

被引:47
|
作者
Qin, Junxian [1 ]
Pei, Yun [1 ]
Zheng, Yue [1 ]
Ye, Daiqi [1 ,2 ,3 ]
Hu, Yun [1 ,2 ,3 ]
机构
[1] South China Univ Technol, Sch Environm & Energy, Guangzhou 510006, Peoples R China
[2] Guangdong Prov Key Lab Atmospher Environm & Pollut, Guangzhou 510006, Peoples R China
[3] Minist Educ, Key Lab Pollut Control & Ecosyst Restorat Ind Clus, Guangzhou 510006, Peoples R China
来源
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY | 2023年 / 325卷
基金
中国国家自然科学基金;
关键词
Metal organic framework derivative; Photocatalysis; Volatile organic compounds; Bacteriostat; Oxygen reduction; METAL-ORGANIC-FRAMEWORK; COORDINATIVELY UNSATURATED SITES; HETEROGENEOUS CATALYSTS; FACILE SYNTHESIS; WASTE-WATER; MIL-100(FE); ACETALIZATION; DEGRADATION; NANOSHEETS; OXIDATION;
D O I
10.1016/j.apcatb.2022.122346
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fe-MOF derivative (M-300) is successfully prepared by thermal treatment using MIL-100(Fe) as a precursor. The resulting M-300 catalyst displays excellent performance in the degradation of volatile organic compounds (VOCs) and the bacteriostasis to Escherichia coli under the visible light. In addition, the catalyst also exhibits the capacity of acetaldehyde degradation under actual sunlight. The high activity is attributed to the abundant exposure of the unsaturated Fe2+ active site, which can significantly promote the transfer of photogenerated electron and the oxygen reduction process, thus improving the efficiency of the entire photocatalytic oxidation reaction. This work shows the application prospect of MOFs derivatives in the field of indoor photocatalytic purification, and also provides a new insight into the study of catalyst modification in photocatalytic degradation of pollutants.
引用
收藏
页数:9
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