Facile fabrication of ultra-light N-doped-rGO/g-C3N4 for broadband microwave absorption

被引:13
|
作者
Su, Qiang [1 ,2 ]
He, Yunfei [1 ]
Liu, Dongdong [1 ]
Jia, Kun [3 ]
Xia, Long [1 ]
Huang, Xiaoxiao [4 ]
Zhong, Bo [1 ]
机构
[1] Harbin Inst Technol Weihai, Sch Mat Sci & Engn, Weihai 264209, Peoples R China
[2] Weihai Yunshan Technol Co LTD, Weihai 264200, Peoples R China
[3] NO33 Res Inst China Elect Technol Grp Corp, Shanxi Key Lab Electromagnet Protect Mat & Technol, Taiyuan 030032, Peoples R China
[4] Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
N-doped-rGO; Impedance matching; Interfacial polarization; Ultra-light; Excellent microwave absorption; REDUCED GRAPHENE OXIDE; DOPED GRAPHENE; SOLVOTHERMAL SYNTHESIS; HOLLOW MICROSPHERES; CARBON NANOTUBES; NITROGEN; COMPOSITES; NANOCOMPOSITES; BORON; LIGHTWEIGHT;
D O I
10.1016/j.jcis.2023.06.151
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
"Thin thickness", "lightweight", "wide absorption bandwidth" and "strong absorption" are the new standards of contemporary science and technology for microwave absorption(MA) material. In this study, N-doped-rGO/g-C3N4 MA material was prepared for the first time by simple heat treatment, which the N atoms were doped into rGO and g-C3N4 was dispersed on the surface of N-doped-rGO, and its density is only 0.035 g/cm3. The impedance matching of the N-doped-rGO/g-C3N4 composite was well adjusted by decreasing the dielectric constant and attenuation constant due to the g-C3N4 semiconductor property and the graphite-like structure. Moreover, the distribution of g-C3N4 among N-doped-rGO sheets can produce more polarization effect and relaxation effect by increasing the lamellar spacing. Furthermore, the polarization loss of N-doped-rGO/g-C3N4 could be increased successfully by doping N atoms and g-C3N4. Ultimately, the MA property of N-doped-rGO/g-C3N4 composite was optimized significantly, with a loading of 5 wt%, the N-doped-rGO/g-C3N4 composite exhibited the RLmin of-49.59 dB and the effective absorption bandwidth could reach 4.56 GHz when the thickness was only 1.6 mm. The "thin thickness", "lightweight", "wide absorption bandwidth" and "strong ab-sorption" of MA material are actually achieved by the N-doped-rGO/g-C3N4.
引用
收藏
页码:47 / 57
页数:11
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