Removal of highly concentrated methylene blue dye by cellulose nanofiber biocomposites

The contamination of water by dyes in high concentrations is a worldwide concern, and it has prompted the development of efficient, economical, and environmentally friendly materials and technologies for water puri-fication. The hydration and adsorption capacity for methylene blue (MB) in biocomposites (BCs) based on cel-lulose nanofiber (CNF) (0 to 2 wt%) were studied. BCs were synthesized through a simple and straightforward route and characterized by spectroscopy, microscopic techniques and thermogravimetric analysis, among others. Hydration studies showed that BCs prepared with 2 wt% of CNF can absorb large volumes of water, approxi-mately 2274 % in the case of poly 2-acrylamide-2-methyl-1-propanesulfonic acid (PAMPS)-CNF and 2408 % in poly sodium 4-styrene sulfonate (PSSNa)-CNF. These BCs showed outstanding adsorption capacity for highly concentrated MB solutions (4536 mg g-1 PAMPS-CNF and 11,930 mg g-1 PSSNa-CNF). It was confirmed that the adsorption mechanism is through electrostatic interactions. Finally, BCs showed high MB adsorption efficiency after several sorption-desorption cycles and on a simulated textile effluent. Furthermore, the theoretical results showed a preferential interaction between MB and the semiflexible polymer chains at the lowest energy setting. The development and study of a new adsorbent material with high MB removal performance that is easy to prepare, economical and reusable for potential use in water purification treatments was successfully achieved.