Removal of highly concentrated methylene blue dye by cellulose nanofiber biocomposites

被引:22
作者
Oyarce, Estefania [1 ]
Cantero-Lopez, Plinio [2 ,3 ,4 ]
Roa, Karina [1 ]
Boulett, Andres [1 ]
Yanez, Osvaldo [5 ,6 ]
Santander, Paola [1 ]
Pizarro, Guadalupe del C. [7 ]
Sanchez, Julio [1 ]
机构
[1] Univ Santiago Chile USACH, Fac Quim & Biol, Dept Ciencias Ambiente, Santiago, Chile
[2] Univ Andres Bello, Fac Ciencias Exactas, Dept Ciencias, Quim, Vina Del Mar, Chile
[3] Univ Andres Bello, Fac Ciencias Exactas, Ctr Appl Nanosci CANS, Santiago, Chile
[4] Univ Andres Bello, Fac Ciencias Exactas, PhD program Mol Phys Chem, Relativist Mol Phys Grp ReMoPh, Santiago, Chile
[5] Univ Amer, Fac Ingn & Negocios, Santiago, Chile
[6] Ctr New Drugs Hypertens CENDHY, Santiago, Chile
[7] Univ Tecnol Metropolitana, Dept Quim, JP Alessandri 1242, Santiago, Chile
关键词
Biocomposites; Cellulose nanofiber; Dyes; Hydrogels; Wastewater; CATIONIC DYES; AQUEOUS-SOLUTIONS; SULFONIC-ACID; PHOTOCATALYTIC DEGRADATION; ENHANCED ADSORPTION; COMPOSITE HYDROGEL; FUNCTIONAL-GROUPS; BEADS ISOTHERM; GRAPHENE OXIDE; FORCE-FIELD;
D O I
10.1016/j.ijbiomac.2023.124045
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The contamination of water by dyes in high concentrations is a worldwide concern, and it has prompted the development of efficient, economical, and environmentally friendly materials and technologies for water puri-fication. The hydration and adsorption capacity for methylene blue (MB) in biocomposites (BCs) based on cel-lulose nanofiber (CNF) (0 to 2 wt%) were studied. BCs were synthesized through a simple and straightforward route and characterized by spectroscopy, microscopic techniques and thermogravimetric analysis, among others. Hydration studies showed that BCs prepared with 2 wt% of CNF can absorb large volumes of water, approxi-mately 2274 % in the case of poly 2-acrylamide-2-methyl-1-propanesulfonic acid (PAMPS)-CNF and 2408 % in poly sodium 4-styrene sulfonate (PSSNa)-CNF. These BCs showed outstanding adsorption capacity for highly concentrated MB solutions (4536 mg g-1 PAMPS-CNF and 11,930 mg g-1 PSSNa-CNF). It was confirmed that the adsorption mechanism is through electrostatic interactions. Finally, BCs showed high MB adsorption efficiency after several sorption-desorption cycles and on a simulated textile effluent. Furthermore, the theoretical results showed a preferential interaction between MB and the semiflexible polymer chains at the lowest energy setting. The development and study of a new adsorbent material with high MB removal performance that is easy to prepare, economical and reusable for potential use in water purification treatments was successfully achieved.
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页数:17
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