Lewis acid catalysed polymerisation of cyclopentenone

被引：1

作者：

Dissanayake, Deepamali ^{[1
]}

Draper, Alysia ^{[1
]}

Liu, Zhizhou ^{[1
,2
]}

Jaunnoo, Neelofur ^{[1
]}

Haven, Joris J. ^{[1
]}

Forsyth, Craig ^{[1
]}

McKay, Alasdair I. ^{[1
]}

Junkers, Tanja ^{[1
]}

Vidovic, Dragoslav ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton 3800, Australia

[2] Chinese Acad Sci, Suzhou Inst Biomed Engn & Technol, Suzhou 215163, Peoples R China

来源：

CHEMICAL SCIENCE | 2024年 / 15卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

Compendex;

D O I：

10.1039/d3sc05186b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A modest structural change of a beta-diketiminate-supported aluminium complex leads to dramatic differences in the reactivity towards cyclopentenone. While the bulkier complex efficiently executes Diels Alder transformations the smaller analogue performs unique polymerisation of this substrate. This observation appears to be unprecedented in the chemistry of Lewis acids and cyclic dienophiles as it represents a unique way to polymerise a functionalised olefin. A modest structural change of a beta-diketiminate-supported aluminium complex leads to dramatic differences in the reactivity towards cyclopentenone.

引用

收藏

页码：639 / 643

页数：5

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