Annulation Reaction of Quinoxalin-2(1H)-ones Initiated by Electrochemical Decarboxylation of N-Arylglycines

被引：13

作者：

Cui, Jian-Feng ^{[1
]}

Zhong, Wei-Qiang ^{[1
]}

Huang, Jing-Mei ^{[1
]}

机构：

[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 02期

基金：

中国国家自然科学基金;

关键词：

ORGANIC ELECTROSYNTHESIS; DERIVATIVES; TRIFLUOROMETHYLATION; INHIBITORS;

D O I：

10.1021/acs.joc.2c02654

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new methodology for the synthesis of tetrahydroimidazo[1,5-a]quinoxalin-4(5H)-ones has been accomplished through annulation of quinoxalin-2(1H)-ones initiated by electrochemical decarboxylation of N-arylglycines catalyzed by ferrocene. With a pair of oxidative and reductive processes occurring among the substrates and intermediates instead of on the electrodes, the electricity consumption was decreased.

引用

页码：1147 / 1154

页数：8

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