Photocatalytic generation of 1,4-disubstituted 1,2,3-triazoles under metal, oxidant and azide-free conditions

被引：5

作者：

Liu, Changhong ^{[1
]}

Abdukerem, Dilshat ^{[1
]}

Zhu, Wenli ^{[1
]}

Xia, Kun ^{[1
]}

Mao, Zechuan ^{[1
]}

Abdukader, Ablimit ^{[1
]}

机构：

[1] Xinjiang Univ, Coll Chem, State Key Lab Chem & Utilizat Carbon Based Energy, Urumqi 830017, Xinjiang, Peoples R China

来源：

GREEN SYNTHESIS AND CATALYSIS | 2024年 / 5卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Photocatalytic; Triazoles; Cycloaddition reaction; Allyl-type radicals; AROMATIC AZO-COMPOUNDS; ONE-POT SYNTHESIS; N-BOND FORMATION; REGIOSPECIFIC SYNTHESIS; ALKYNE CYCLOADDITION; CLICK CHEMISTRY; GREEN SYNTHESIS; C-N; TOSYLHYDRAZONES; CATALYST;

D O I：

10.1016/j.gresc.2023.05.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Available online A mild and efficient photocatalytic-induced radical method has been developed for [4 thorn 1] cycloaddition reaction of 1,4-disubstituted 1,2,3-triazoles with N-tosylhydrazides and primary amines. The reaction is catalyzed by 20 mol% of I2 under metal, azide and oxidant-free conditions. The method is based upon the photocatalytic generation of allyl-type radicals, followed by the iodine-catalyzed production of azoalkenes, which react rapidly with various anilines.

引用

页码：62 / 67

页数：6

共 50 条

[21] 'Green' synthesis of 1,4-disubstituted 5-iodo-1,2,3-triazoles under neat conditions, and an efficient approach of construction of 1,4,5-trisubstituted 1,2,3-triazoles in one pot
Wang, Dong
Chen, Si
Chen, Baohua
TETRAHEDRON LETTERS, 2014, 55 (51) : 7026 - 7028
[22] Efficient synthesis, antitubercular and antimicrobial evaluation of 1,4-disubstituted 1,2,3-triazoles with amide functionality
Kaushik, C. P.
Pahwa, Ashima
Singh, Dharmendra
Kumar, Krishan
Luxmi, Raj
MONATSHEFTE FUR CHEMIE, 2019, 150 (06): : 1127 - 1136
[23] Recent Catalysts Used in the Synthesis of 1,4-Disubstituted 1,2,3-Triazoles by Heterogeneous and Homogeneous Methods
Noriega, Saul
Leyva, Elisa
Moctezuma, Edgar
Flores, Luisa
Loredo-Carrillo, Silvia
CURRENT ORGANIC CHEMISTRY, 2020, 24 (05) : 536 - 549
[24] Synthesis and antimicrobial evaluation of some novel thiomorpholine derived 1,4-disubstituted 1,2,3-triazoles
Battula, Kumaraswamy
Narsimha, Sirassu
Nagavelli, Vasudevareddy
Bollepelli, Priyanka
Rao, Mutheneni Srinivasa
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2016, 81 (03) : 233 - 242
[25] The Use of Copper Flow Reactor Technology for the Continuous Synthesis of 1,4-Disubstituted 1,2,3-Triazoles
Bogdan, Andrew R.
Sach, Neal W.
ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (06) : 849 - 854
[26] Recent Advancements in 1,4-Disubstituted 1H-1,2,3-Triazoles as Potential Anticancer Agents
Lal, Kashmiri
Yadav, Pinki
ANTI-CANCER AGENTS IN MEDICINAL CHEMISTRY, 2018, 18 (01) : 21 - 37
[27] SYNTHESIS OF 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES VIA CLICK REACTION IN MICRO FLOW REACTOR
Lei, Ming
Hu, Ruijun
Wang, Yanguang
Zhang, Hong
HETEROCYCLES, 2014, 88 (02) : 1511 - 1517
[28] Recent progress in the Cu-catalyzed multicomponent synthesis of 1,4-disubstituted 1,2,3-triazoles
Anand, Akash
Kumar, Rajneesh
Maity, Jyotirmoy
Maikhuri, Vipin K. K.
SYNTHETIC COMMUNICATIONS, 2023, 53 (05) : 345 - 375
[29] Cuprous oxide on charcoal-catalyzed ligand-free synthesis of 1,4-disubstituted 1,2,3-triazoles via click chemistry
Lopez-Ruiz, Heraclio
Emilio de la Cerda-Pedro, Jose
Rojas-Lima, Susana
Perez-Perez, Imelda
Viridiana Rodriguez-Sanchez, Brianda
Santillan, Rosa
Coreno, Oscar
ARKIVOC, 2013, : 139 - 164
[30] Synthesis and antimicrobial evaluation of 1,4-disubstituted 1,2,3-triazoles with aromatic ester functionality
Kaushik, C. P.
Kumar, Krishan
Singh, S. K.
Singh, Dharmendra
Saini, Sangita
ARABIAN JOURNAL OF CHEMISTRY, 2016, 9 (06) : 865 - 871

← 1 2 3 4 5 →