Synthesis of hierarchical structure MXene/PANI composite hybrid electrodes for supercapacitors

被引:14
作者
Chen, Tao [1 ,2 ]
Li, Man [1 ]
Li, Yang [1 ]
Song, Seunghyun [1 ]
Kim, Jihyun [1 ]
Bae, Joonho [1 ]
机构
[1] Gachon Univ, Dept Phys, Seongnam 461701, Gyeonggi Do, South Korea
[2] Changzhou Vocat Inst Ind Technol, Sch Mat Engn, 28 Mingxin Middle Rd,Wujing Dist, Changzhou, Jiangsu, Peoples R China
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2023年 / 290卷
基金
新加坡国家研究基金会;
关键词
Ti3C2Tx; PANI; MXene/PANI; Electrochemical performance; Supercapacitor; THERMAL-STABILITY; ENERGY-STORAGE; CARBIDE MXENE;
D O I
10.1016/j.mseb.2023.116354
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
An MXene (Ti3C2Tx)/polyaniline (PANI) composite was successfully synthesized by the etching of Ti3AlC2 MAX and a simple polymerization process. In the obtained MXene/PANI composite, a dense covering of PANI appears on the surface and interlayers of two-dimensional MXene owing to electrostatic interaction. The electrochemical properties of Ti3C2Tx MXene, PANI, and MXene/PANI composite electrodes were investigated. The crystal phase data and morphology of the samples were observed by X-ray diffraction analysis, scanning electron microscopy, and transmission electron microscopy. The electrochemical properties of the electrode materials were measured in a three-electrode system using cyclic voltammetry, galvanostatic charge/discharge measurements, and electrochemical impedance spectroscopy. The results demonstrate that the MXene/PANI electrode has a higher specific capacitance of 458.3 Fg(-1) at a scan rate of 5 mVs(-1) compared to the pure Ti3C2Tx MXene and PANI electrodes and a capacitance retention of 95.5 % after 1000 cycles at a current density of 5 Ag-1, indicating that MXene/PANI can be regarded as a promising electrode material for supercapacitors.
引用
收藏
页数:8
相关论文
共 35 条
[21]   A review of the control of pore structure in MgO-templated nanoporous carbons [J].
Morishita, T. ;
Tsumura, T. ;
Toyoda, M. ;
Przepiorski, J. ;
Morawski, A. W. ;
Konno, H. ;
Inagaki, M. .
CARBON, 2010, 48 (10) :2690-2707
[22]   MXene-Based Electrode with Enhanced Pseudocapacitance and Volumetric Capacity for Power-Type and Ultra-Long Life Lithium Storage [J].
Niu, Shanshan ;
Wang, Zhiyu ;
Yu, Mingliang ;
Yu, Mengzhou ;
Xiu, Luyang ;
Wang, Song ;
Wu, Xianhong ;
Qiu, Jieshan .
ACS NANO, 2018, 12 (04) :3928-3937
[23]   3D Printing of Additive-Free 2D Ti3C2Tx (MXene) Ink for Fabrication of Micro-Supercapacitors with Ultra-High Energy Densities [J].
Orangi, Jafar ;
Hamade, Fatima ;
Davis, Virginia A. ;
Beidaghi, Majid .
ACS NANO, 2020, 14 (01) :640-650
[24]   Enhanced electrochemical behavior and hydrophobicity of crystalline polyaniline@graphene nanocomposite synthesized at elevated temperature [J].
Parveen, Nazish ;
Mahato, Neelima ;
Ansari, Mohd Omaish ;
Cho, Moo Hwan .
COMPOSITES PART B-ENGINEERING, 2016, 87 :281-290
[25]   All-MXene (2D titanium carbide) solid-state microsupercapacitors for on-chip energy storage [J].
Peng, You-Yu ;
Akuzum, Bilen ;
Kurra, Narendra ;
Zhao, Meng-Qiang ;
Alhabe, Mohamed ;
Anasori, Babak ;
Kumbur, Emin Caglan ;
Alshareef, Husam N. ;
Ger, Ming-Der ;
Gogotsi, Yury .
ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (09) :2847-2854
[26]   Two-dimensional materials in enhancement of membrane-based lithium recovery from metallic-ions-rich wastewaters: A review [J].
Rahighi, Reza ;
Hosseini-Hosseinabad, Seyed Morteza ;
Zeraati, Ali Shayesteh ;
Suwaileh, Wafa ;
Norouzi, Ali ;
Panahi, Mohammad ;
Gholipour, Somayeh ;
Karaman, Ceren ;
Akhavan, Omid ;
Khollari, Mohammad Amin Razmjoo ;
Vinu, Ajayan ;
Rashidi, Alimorad ;
Abdala, Ahmed ;
Karimi-Maleh, Hassan ;
Orooji, Yasin .
DESALINATION, 2022, 543
[27]   Conducting-polymer-based supercapacitor devices and electrodes [J].
Snook, Graeme A. ;
Kao, Pon ;
Best, Adam S. .
JOURNAL OF POWER SOURCES, 2011, 196 (01) :1-12
[28]   Thick and freestanding MXene/PANI pseudocapacitive electrodes with ultrahigh specific capacitance [J].
VahidMohammadi, Armin ;
Moncada, Jorge ;
Chen, Hengze ;
Kayali, Emre ;
Orangi, Jafar ;
Carrero, Carlos A. ;
Beidaghi, Majid .
JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (44) :22123-22133
[29]   Unraveling and Regulating Self-Discharge Behavior of Ti3C2Tx MXene-Based Supercapacitors [J].
Wang, Zixing ;
Xu, Zhong ;
Huang, Haichao ;
Chu, Xiang ;
Xie, Yanting ;
Xiong, Da ;
Yan, Cheng ;
Zhao, Haibo ;
Zhang, Haitao ;
Yang, Weiqing .
ACS NANO, 2020, 14 (04) :4916-4924
[30]   Flexible MXene-graphene electrodes with high volumetric capacitance for integrated co-cathode energy conversion/storage devices [J].
Xu, Shuaikai ;
Wei, Guodong ;
Li, Junzhi ;
Han, Wei ;
Gogotsi, Yury .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (33) :17442-17451