New Markers for Determining the Chemical and Isomeric Composition of Carotenoids by Raman Spectroscopy

被引：0

作者：

Vasimov, D. D. ^{[1
]}

Ashikhmin, A. A. ^{[2
]}

Bolshakov, M. A. ^{[2
]}

Moskovsky, M. N. ^{[3
]}

Gudkov, S. V. ^{[1
,3
]}

Yanykin, D. V. ^{[1
,2
]}

Novikov, V. S. ^{[1
]}

机构：

[1] Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow, Russia

[2] Russian Acad Sci, Inst Basic Biol Problems, Pushchino Sci Ctr Biol Res, Pushchino 142290, Moscow Oblast, Russia

[3] Fed Sci Agroengn Ctr VIM, Moscow, Russia

来源：

DOKLADY PHYSICS | 2023年 / 68卷 / 11期

关键词：

Raman spectroscopy; density functional theory; carotenoids; pigments; cis-trans isomerism; BETA-CAROTENE; RESONANCE RAMAN; ALL-TRANS; GEOMETRICAL-ISOMERS; INFRARED-SPECTRA; 15-CIS ISOMERS; LYCOPENE; CONFIGURATIONS; COMPLEXES;

D O I：

10.1134/S1028335823110071

中图分类号：

O3 [力学];

学科分类号：

08 ; 0801 ;

摘要：

The experimental and calculated on the basis of density functional theory Raman spectra of plant and bacterial carotenoids (neurosporene, spheroidene, lycopene, spirilloxanthin, beta-carotene, lutein, zeta-carotene, alpha-carotene, and gamma-carotene) are analyzed. A number of characteristic features in the Raman spectra of carotenoids are described for the first time, which make it possible to determine the structure of the end groups of molecules and to distinguish their isomers.

引用

页码：359 / 365

页数：7

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