Applications of X-ray Absorption Fine Structure Spectroscopy in the Photocatalytic Conversion of Small Molecules

被引：3
作者：
Du, Peipei [1 ,2 ]
Si, Rui [3 ,4 ]
Li, Zhaosheng [1 ,2 ]
Zou, Zhigang [1 ,2 ]
机构：
[1] Nanjing Univ, Coll Engn & Appl Sci, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Jiangsu Key Lab Nano Technol, Nanjing 210093, Jiangsu, Peoples R China
[3] Inst Adv Sci Facil, Shenzhen 518107, Guangdong, Peoples R China
[4] Sun Yat Sen Univ, Sch Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China
来源：
ACS CATALYSIS | 2023年 / 13卷 / 10期
基金：
中国国家自然科学基金;
关键词：
XAFS; small-molecule conversion; photocatalytic water splitting; photocatalytic CO2 reduction; photodriven N2 fixation; IN-SITU; NITROGEN-FIXATION; CARBON-DIOXIDE; CO2; PHOTOREDUCTION; OXYGEN VACANCIES; RECENT PROGRESS; WATER; REDUCTION; LIGHT; CATALYSIS;
D O I：
10.1021/acscatal.2c06413
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The conversion of small molecules (H2, CO, CH4, NH3, etc.) in energy-related systems offers enormous potential in the conversion and storage of renewable energy. X-ray absorption fine structure spectroscopy (XAFS) is indispensable in probing the geometric and electronic microenvironments of catalysts, providing the necessary assistance to reveal reaction mechanisms and active sites at the atomic level. Our summary highlights the recent advancements in utilizing XAFS in the photocatalytic conversion of small molecules, including but not limited to water splitting of H2 production, CO2 reduction, and N2 fixation. Furthermore, we discuss future prospects for the development of XAFS-based combined techniques to guide their utilization.
引用
收藏
页码：6690 / 6703
页数：14
相关论文
共 156 条
  • [1] EXAFS characterization of supported metal-complex and metal-cluster catalysts made from organometallic precursors
    Alexeev, O
    Gates, BC
    [J]. TOPICS IN CATALYSIS, 2000, 10 (3-4) : 273 - 293
  • [2] Selective Etching of Silicon from Ti3SiC2 (MAX) To Obtain 2D Titanium Carbide (MXene)
    Alhabeb, Mohamed
    Maleski, Kathleen
    Mathis, Tyler S.
    Sarycheva, Asia
    Hatter, Christine B.
    Uzun, Simge
    Levitt, Ariana
    Gogotsi, Yury
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (19) : 5444 - 5448
  • [3] Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2
    Aresta, Michele
    Dibenedetto, Angela
    Angelini, Antonella
    [J]. CHEMICAL REVIEWS, 2014, 114 (03) : 1709 - 1742
  • [4] Understanding Structure-Property Relationships of MoO3-Promoted Rh Catalysts for Syngas Conversion to Alcohols
    Asundi, Arun S.
    Hoffman, Adam S.
    Bothra, Pallavi
    Boubnov, Alexey
    Vila, Fernando D.
    Yang, Nuoya
    Singh, Joseph A.
    Zeng, Li
    Raiford, James A.
    Abild-Pedersen, Frank
    Bare, Simon R.
    Bent, Stacey F.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (50) : 19655 - 19668
  • [5] Photochemical Nitrogen Conversion to Ammonia in Ambient Conditions with FeMoS-Chalcogels
    Banerjee, Abhishek
    Yuhas, Benjamin D.
    Margulies, Eric A.
    Zhang, Yongbo
    Shim, Yurina
    Wasielewski, Michael R.
    Kanatzidis, Mercouri G.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (05) : 2030 - 2034
  • [6] Significant Advances in C1 Catalysis: Highly Efficient Catalysts and Catalytic Reactions
    Bao, Jun
    Yang, Guohui
    Yoneyama, Yoshiharu
    Tsubaki, Noritatsu
    [J]. ACS CATALYSIS, 2019, 9 (04) : 3026 - 3053
  • [7] Light-driven dinitrogen reduction catalyzed by a CdS:nitrogenase MoFe protein biohybrid
    Brown, Katherine A.
    Harris, Derek F.
    Wilker, Molly B.
    Rasmussen, Andrew
    Khadka, Nimesh
    Hamby, Hayden
    Keable, Stephen
    Dukovic, Gordana
    Peters, John W.
    Seefeldt, Lance C.
    King, Paul W.
    [J]. SCIENCE, 2016, 352 (6284) : 448 - 450
  • [8] Cai M., NAT ENERGY
  • [9] Contributions to accelerating atmospheric CO2 growth from economic activity, carbon intensity, and efficiency of natural sinks
    Canadell, Josep G.
    Le Quéré, Corinne
    Raupach, Michael R.
    Field, Christopher B.
    Buitenhuis, Erik T.
    Ciais, Philippe
    Conway, Thomas J.
    Gillett, Nathan P.
    Houghton, R. A.
    Marland, Gregg
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (47) : 18866 - 18870
  • [10] Single-atom gold oxo-clusters prepared in alkaline solutions catalyse the heterogeneous methanol self-coupling reactions
    Cao, Sufeng
    Yang, Ming
    Elnabawy, Ahmed O.
    Trimpalis, Antonios
    Li, Sha
    Wang, Chongyang
    Goltl, Florian
    Chen, Zhihengyu
    Liu, Jilei
    Shan, Junjun
    Li, Mengwei
    Haas, Terry
    Chapman, Karena W.
    Lee, Sungsik
    Allard, Lawrence F.
    Mavrikakis, Manos
    Flytzani-Stephanopoulos, Maria
    [J]. NATURE CHEMISTRY, 2019, 11 (12) : 1098 - 1105
12345678910