PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO2 in the presence of silanes

被引：11
作者：
Song, Zijie [1 ]
Liu, Jun [1 ]
Xing, Shuya [1 ]
Shao, Xinxin [1 ]
Li, Jiayun [1 ]
Peng, Jiajian [1 ]
Bai, Ying [1 ]
机构：
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Mat Technol Zhejiang Prov, Key Lab Organosilicon Chem & Mat Technol,Minist Ed, Hangzhou 311121, Zhejiang, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 04期
基金：
美国国家科学基金会;
关键词：
CARBON-DIOXIDE; FORMIC-ACID; ATM; HYDROSILYLATION; TRANSFORMATION; METHYLATION; HYDROSILANE; FORMAMIDES; REDUCTION; ACTIVATION;
D O I：
10.1039/d2ob01986h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The sustainable catalytic transformation of carbon dioxide into valuable fine chemicals with high efficiency is a global challenge as although CO2 is an abundant, nontoxic, and sustainable carbon feedstock it is also the most important factor behind the Greenhouse Effect. We describe herein a PNP-type ligand-enabled copper-catalyzed N-formylation of amines utilizing CO2 as the building block in the presence of hydrosilane as the reductant. Our current protocol featured newly synthesized PNP-type ligands with broad substrate scope under mild reaction conditions.
引用
收藏
页码：832 / 837
页数：6
相关论文
共 52 条
  • [1] Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2
    Aresta, Michele
    Dibenedetto, Angela
    Angelini, Antonella
    [J]. CHEMICAL REVIEWS, 2014, 114 (03) : 1709 - 1742
  • [2] Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
    Birdja, Yuvraj Y.
    Perez-Gallent, Elena
    Figueiredo, Marta C.
    Gottle, Adrien J.
    Calle-Vallejo, Federico
    Koper, Marc T. M.
    [J]. NATURE ENERGY, 2019, 4 (09) : 732 - 745
  • [3] A Viewpoint on Chemical Reductions of Carbon-Oxygen Bonds in Renewable Feedstocks Including CO2 and Biomass
    Chauvier, Clement
    Cantat, Thibault
    [J]. ACS CATALYSIS, 2017, 7 (03): : 2107 - 2115
  • [4] Advance and Prospective on CO2 Activation and Transformation Strategy
    Chen, Kaihong
    Li, Hongru
    He, Liangnian
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (08) : 2195 - 2207
  • [5] Chen X.-W., 2022, CHEM TRANSFORMATIONS, P1217, DOI [10.1002/9783527831883.ch27, DOI 10.1002/9783527831883.CH27]
  • [6] Nickel-Catalyzed Asymmetric Reductive Carbo-Carboxylation of Alkenes with CO2
    Chen, Xiao-Wang
    Yue, Jun-Ping
    Wang, Kuai
    Gui, Yong-Yuan
    Niu, Ya-Nan
    Liu, Jie
    Ran, Chuan-Kun
    Kong, Wangqing
    Zhou, Wen-Jun
    Yu, Da-Gang
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (25) : 14068 - 14075
  • [7] Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2
    Chen, Xiao-Wang
    Zhu, Lei
    Gui, Yong-Yuan
    Jing, Ke
    Jiang, Yuan-Xu
    Bo, Zhi-Yu
    Lan, Yu
    Li, Jing
    Yu, Da-Gang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (47) : 18825 - 18835
  • [8] Generation of Dihydrogen Molecule and Hydrosilylation of Carbon Dioxide Catalyzed by Zinc Hydride Complex: Theoretical Understanding and Prediction
    Deshmukh, Milind Madhusudan
    Sakaki, Shigeyoshi
    [J]. INORGANIC CHEMISTRY, 2014, 53 (16) : 8485 - 8493
  • [9] Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines
    Frogneux, Xavier
    Jacquet, Olivier
    Cantat, Thibault
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (06) : 1529 - 1533
  • [10] Nickel-Catalyzed Hydrosilylation of CO2 in the Presence of Et3B for the Synthesis of Formic Acid and Related Formates
    Gonzalez-Sebastian, Lucero
    Flores-Alamo, Marcos
    Garcia, Juventino J.
    [J]. ORGANOMETALLICS, 2013, 32 (23) : 7186 - 7194
123456