PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO2 in the presence of silanes

被引：11
|
作者：
Song, Zijie [1 ]
Liu, Jun [1 ]
Xing, Shuya [1 ]
Shao, Xinxin [1 ]
Li, Jiayun [1 ]
Peng, Jiajian [1 ]
Bai, Ying [1 ]
机构：
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Mat Technol Zhejiang Prov, Key Lab Organosilicon Chem & Mat Technol,Minist Ed, Hangzhou 311121, Zhejiang, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 04期
基金：
美国国家科学基金会;
关键词：
CARBON-DIOXIDE; FORMIC-ACID; ATM; HYDROSILYLATION; TRANSFORMATION; METHYLATION; HYDROSILANE; FORMAMIDES; REDUCTION; ACTIVATION;
D O I：
10.1039/d2ob01986h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The sustainable catalytic transformation of carbon dioxide into valuable fine chemicals with high efficiency is a global challenge as although CO2 is an abundant, nontoxic, and sustainable carbon feedstock it is also the most important factor behind the Greenhouse Effect. We describe herein a PNP-type ligand-enabled copper-catalyzed N-formylation of amines utilizing CO2 as the building block in the presence of hydrosilane as the reductant. Our current protocol featured newly synthesized PNP-type ligands with broad substrate scope under mild reaction conditions.
引用
收藏
页码：832 / 837
页数：6
相关论文
共 50 条
  • [1] Copper-catalyzed N-formylation of amines with CO2 under ambient conditions
    Zhang, Suqi
    Mei, Qingqing
    Liu, Hangyu
    Liu, Huizhen
    Zhang, Zepeng
    Han, Buxing
    RSC ADVANCES, 2016, 6 (38) : 32370 - 32373
  • [2] Photocatalytic N-Formylation of CO2 with Amines Catalyzed by Diethyltriamine Pentaacetic Acid
    Yuan, Xuexin
    Zhou, Qiqi
    Chen, Yu
    Yang, Hai-Jian
    Jiang, Qingqing
    Hu, Juncheng
    Guo, Cun-Yue
    C-JOURNAL OF CARBON RESEARCH, 2024, 10 (03):
  • [3] Triethylamine Catalyzed Reductive CO2 to Form N-Formylation of Amines and Hydrazides
    Wei, Xiu-Zhi
    Lu, Qiqi
    Liu, Jianguo
    Ma, Longlong
    CHEMISTRYSELECT, 2022, 7 (27):
  • [4] Iron-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2
    Li, Wen-Duo
    Zhu, Dao-Yong
    Li, Gang
    Chen, Jie
    Xia, Ji-Bao
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (22) : 5098 - 5104
  • [5] Phosphonium-Salt-Catalyzed N-Methylation and N-Formylation of Amines with CO2
    Ren, Changyue
    Spannenberg, Anke
    Werner, Thomas
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2024, 12 (29): : 10969 - 10977
  • [6] DBU-Catalyzed Selective N-Methylation and N-Formylation of Amines with CO2 and Polymethylhydrosiloxane
    Li, Gang
    Chen, Jie
    Zhu, Dao-Yong
    Chen, Ye
    Xia, Ji-Bao
    ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (12) : 2364 - 2369
  • [7] Can CO2 be a catalyst? Yes, CO2-catalyzed N-formylation of aliphatic amines with DMF
    Chen, Xiao-Chao
    Guo, Lin
    Shi, Guang-Hui
    Zhao, Kai-Chun
    Lu, Yong
    Liu, Ye
    Molecular Catalysis, 2022, 528
  • [8] Can CO2 be a catalyst? Yes, CO2-catalyzed N-formylation of aliphatic amines with DMF
    Chen, Xiao-Chao
    Guo, Lin
    Shi, Guang-Hui
    Zhao, Kai-Chun
    Lu, Yong
    Liu, Ye
    MOLECULAR CATALYSIS, 2022, 528
  • [9] Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H2 and CO2
    Zhang, Lei
    Han, Zhaobin
    Zhao, Xiaoyu
    Wang, Zheng
    Ding, Kuiling
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (21) : 6186 - 6189
  • [10] Selective N-Formylation of Amines with H2 and CO2 Catalyzed by Cobalt Pincer Complexes
    Daw, Prosenjit
    Chakraborty, Subrata
    Leitus, Gregory
    Diskin-Posner, Yael
    Ben David, Yehoshoa
    Milstein, David
    ACS CATALYSIS, 2017, 7 (04): : 2500 - 2504
12345