PNP-type ligands enabled copper-catalyzed N-formylation of amines with CO2 in the presence of silanes

被引：14
作者：
Song, Zijie [1 ]
Liu, Jun [1 ]
Xing, Shuya [1 ]
Shao, Xinxin [1 ]
Li, Jiayun [1 ]
Peng, Jiajian [1 ]
Bai, Ying [1 ]
机构：
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Mat Technol Zhejiang Prov, Key Lab Organosilicon Chem & Mat Technol,Minist Ed, Hangzhou 311121, Zhejiang, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2023年 / 21卷 / 04期
基金：
美国国家科学基金会;
关键词：
CARBON-DIOXIDE; FORMIC-ACID; ATM; HYDROSILYLATION; TRANSFORMATION; METHYLATION; HYDROSILANE; FORMAMIDES; REDUCTION; ACTIVATION;
D O I：
10.1039/d2ob01986h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The sustainable catalytic transformation of carbon dioxide into valuable fine chemicals with high efficiency is a global challenge as although CO2 is an abundant, nontoxic, and sustainable carbon feedstock it is also the most important factor behind the Greenhouse Effect. We describe herein a PNP-type ligand-enabled copper-catalyzed N-formylation of amines utilizing CO2 as the building block in the presence of hydrosilane as the reductant. Our current protocol featured newly synthesized PNP-type ligands with broad substrate scope under mild reaction conditions.
引用
收藏
页码：832 / 837
页数：6
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