Microstructure and properties of porous Si3N4 ceramics fabricated by digital light processing combined with spark plasma sintering

被引：11

作者：

Tian, Chong ^{[1
,2
]}

Wang, Qi-Wen ^{[1
,2
]}

Wu, Jia-Min ^{[1
,2
,3
]}

Liu, Chun -Lei ^{[1
,2
]}

Shi, Zhang-Ao ^{[1
,2
]}

Huang, Hai-Lu ^{[1
,2
]}

Lin, Xin ^{[4
,5
]}

Shi, Yu-Sheng ^{[1
,2
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China

[2] Minist Educ, Engn Res Ctr Ceram Mat Addit Mfg, Wuhan 430074, Peoples R China

[3] HUST, Wenzhou Adv Mfg Inst, Wenzhou Key Lab Microwave Commun Mat & Devices, Wenzhou 325035, Peoples R China

[4] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Xian 710072, Shaanxi, Peoples R China

[5] Northwestern Polytech Univ, Key Lab Met High Performance Addit Mfg & Innovat D, MIIT China, Xian 710072, Shaanxi, Peoples R China

来源：

CERAMICS INTERNATIONAL | 2023年 / 49卷 / 24期

基金：

中国国家自然科学基金;

关键词：

Spark plasma sintering; Digital light processing; Properties; MECHANICAL-PROPERTIES; THERMAL-CONDUCTIVITY; NITRIDE; DENSE;

D O I：

10.1016/j.ceramint.2023.10.066

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Sintering process is an important factor affecting the properties of porous Si3N4 ceramics. However, there are few studies on the properties of porous Si3N4 ceramics fabricated by combining digital light processing (DLP) technology and spark plasma sintering (SPS) technology. In this study, a method to prepare porous Si3N4 ceramics by combining DLP with SPS technology was proposed, and ceramic samples were successfully prepared. The effect of sintering temperature and holding time of SPS technology on the microstructure and properties of porous Si3N4 ceramics prepared by DLP technology was discussed. With the increase of sintering temperature from 1600 degrees C to 1700 degrees C, the conversion content of alpha-Si3N4 phase to beta-Si3N4 phase increased from 19.19% to 76.72%. The fracture mode of porous Si3N4 ceramics gradually transformed from intergranular to transgranular. The porosity of Si3N4 ceramics gradually decreased from 40.34 +/- 4.9% to 30.54 +/- 2.7% with opposite trend in bulk density. And the flexural strength increased from 109.1 +/- 7.6 MPa to 249.5 +/- 4.0 MPa. When the sintering temperature was 1700 degrees C, the content of beta-Si3N4 increased first and then remained essentially constant with the increase of holding time from 5 min to 15 min. The porosity increased from 30.54 +/- 2.7% to 35.15 +/- 2.5%, while the variation in bulk density were opposite. And the flexural strength severely decreased from 249.5 +/- 4.0 MPa to 126.1 +/- 7.2 MPa. This research provides valuable insights into the DLP-forming ceramic materials sintered by SPS technology.

引用

页码：40814 / 40820

页数：7

共 39 条

[1] Properties of Si3N4-TiN composites fabricated by spark plasma sintering by using a mixture of Si3N4 and Ti powders [J].