Method optimisation for large scope pesticide multiresidue analysis in bee pollen: A pilot monitoring study

被引：18

作者：

Carrera, Maria Antonietta ^{[1
]}

Sanchez, Lorena Manzano ^{[2
]}

Morales, Maria Murcia ^{[2
]}

Fernandez-Alba, Amadeo R. ^{[2
]}

Hernando, Maria Dolores ^{[1
]}

机构：

[1] CSIC, Dept Desertificat & Geoecol, Expt Stn Arid Zones, Ctra Sacramento S-N, Almeria 04120, Spain

[2] Univ Almeria, Dept Chem & Phys, European Union Reference Lab Pesticide Residues Fr, Ctra Sacramento S-N, Almeria 04120, Spain

来源：

FOOD CHEMISTRY | 2024年 / 436卷

关键词：

Bee pollen; Pesticides; Automated clean-up; Risk assessment; HONEY-BEES; RESIDUES;

D O I：

10.1016/j.foodchem.2023.137652

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Pesticide contamination in emerging foods and supplements is currently a topic of great interest. This study focused on the evaluation of pesticide residues in commercial bee pollen samples to evaluate the risk associated with their consumption. To this end, an automated clean-up method for the pesticide extracts of bee pollen was developed. An LC-MS/MS and a GC-MS/MS method were validated for the analysis of 353 pesticides in 80 bee pollen samples purchased from different countries. The results showed the presence of 77 different pesticide residues in bee pollen, including plant protection chemicals and veterinary treatments. 85 % of the samples were contaminated with pesticides and no relevant differences were found between conventional and organic samples. Pesticide concentrations exceeding the imposed MRL were found in 40 % of the samples, but the risk assessment showed that consumers are not exposed to an unacceptable risk when consuming the evaluated bee pollen.

引用

页数：11

共 32 条

[11] Large pesticide multiresidue screening method by liquid chromatography-Orbitrap mass spectrometry in full scan mode applied to fruit and vegetables [J].

Rajski, Lukasz ;

del Mar Gomez-Ramos, Maria ;

Fernandez-Alba, Amadeo R. .

JOURNAL OF CHROMATOGRAPHY A, 2014, 1360 :119-127

[12] New multiresidue method using solid-phase extraction and gas chromatography-micro-electron-capture detection for pesticide residues analysis in royal jelly [J].

Karazafiris, Emmanouel ;

Menkissoglu-Spiroudi, Urania ;

Thrasyvoulou, Andreas .

JOURNAL OF CHROMATOGRAPHY A, 2008, 1209 (1-2) :17-21

[13] Validation Study on a Method for Multiresidue Analysis of Pesticides in Vegetables and Fruits with Supercritical Fluid Extraction [J].

Uranishi, Katsushige ;

Yamashita, Hirokazu ;

Yamamoto, Keigo .

FOOD HYGIENE AND SAFETY SCIENCE, 2012, 53 (01) :63-74

[14] Validation Study on a Method for Multiresidue Analysis of Pesticides in Cereals and Pulses with Supercritical Fluid Extraction [J].

Uranishi, Katsushige ;

Yamashita, Hirokazu ;

Okayama, Akiko ;

Yamamoto, Keigo .

FOOD HYGIENE AND SAFETY SCIENCE, 2012, 53 (06) :278-290

[15] Multiresidue pesticide analysis in wines by solid-phase extraction and capillary gas chromatography-mass spectrometric detection with selective ion monitoring [J].

Wong, JW ;

Webster, MG ;

Halverson, CA ;

Hengel, MJ ;

Ngim, KK ;

Ebeler, SE .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (05) :1148-1161

[16] HPLC-fluorimetric method for analysis of amino acids in products of the hive (honey and bee-pollen) [J].

Paramás, AMG ;

Bárez, JAG ;

Marcos, CC ;

García-Villanova, RJ ;

Sánchez, JS .

FOOD CHEMISTRY, 2006, 95 (01) :148-156

[17] Analysis of pesticide residues using the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) pesticide multiresidue method in combination with gas and liquid chromatography and tandem mass spectrometric detection [J].

Paula Payá ;

Michelangelo Anastassiades ;

Dorothea Mack ;

Irina Sigalova ;

Bünyamin Tasdelen ;

José Oliva ;

Alberto Barba .

Analytical and Bioanalytical Chemistry, 2007, 389 :1697-1714

[18] Analysis of Pesticide Levels in Honey and Pollen from Irish Honey Bee Colonies Using a Modified Dutch Mini-Luke Method with Gas and Liquid Chromatography-Tandem Mass Spectrometry Detection [J].

Diaz, Marcela A. ;

O'Connell, Darren P. ;

Jordan, Seana ;

O'Connor, Catriona ;

Martin, Paul ;

Jones, Julia C. ;

Garvey, Jim .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2023, 71 (34) :12657-12667

[19] Development of a Multiresidue Method for Pesticide Analysis in Drinking Water by Solid Phase Extraction and Determination by Gas and Liquid Chromatography with Triple Quadrupole Tandem Mass Spectrometry [J].

Donato, Filipe F. ;

Martins, Manoel L. ;

Munaretto, Juliana S. ;

Prestes, Osmar D. ;

Adaime, Martha B. ;

Zanella, Renato .

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2015, 26 (10) :2077-2087

[20] EXPOSURE ASSESSMENT OF PHARMACEUTICAL POWDERS BASED ON AN ENVIRONMENTAL MONITORING METHOD: A PILOT STUDY [J].

Yildirim, Fatma Demircan ;

Ekmekci, Ismail .

MEDYCYNA PRACY, 2020, 71 (06) :649-663

← 1 2 3 4 →