Eco-friendly Ginkgo Leaf Extract as a Green Corrosion Inhibitor to Protect N80 Steel in 1 M HCl

被引:8
|
作者
Zhou, Yingmei [1 ]
Wei, Zhengnan [2 ]
Zhi, Hui [3 ]
Wang, Yue [4 ]
Yao, Xiuquan [3 ]
机构
[1] Shandong Inst Petr & Chem Technol, Sch Chem Engn, Dongying 257601, Peoples R China
[2] SINOPEC, Novel Energy Dev Ctr Shengli Petr Adm, Dongying 257000, Peoples R China
[3] Univ Sci & Technol Beijing, Natl Ctr Mat Serv Safety, Beijing 100083, Peoples R China
[4] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing 100083, Peoples R China
来源
关键词
Green corrosion inhibitor; Plant extract; EIS; Weight loss; MD simulation; MILD-STEEL; CARBON-STEEL; X65; STEEL; COPPER; ACID; MECHANISM;
D O I
10.20964/2022.09.54
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Developing efficient and green corrosion inhibitors is a general trend to replace traditional toxic and harmful corrosion inhibitors, which is not an exception in the corrosion protection and pickling industry in the petroleum industry. Herein, we prepared ginkgo leaf extract (GE) as a green corrosion inhibitor by one-step water extraction. We demonstrated the anti-corrosion performance of GE on N80 steel by combining experiments and calculations. The electrochemical results showed that GE could slow down the corrosion of N80 steel in acidic environment by improving its charge transfer resistance and inhibiting its cathodic and anodic reactions. The weight loss experiments were consistent with the electrochemical test results. We explained the interaction mechanism between GE and N80 steel from the microscopic level based on the Langmuir adsorption model and computer simulation. In short, the 6-hydroxykynurenic acid molecule (from GE) was adsorbed on the surface of N80 steel through benzene rings and heteroatoms in parallel and offered excellent anti-corrosion performance for N80 steel.
引用
收藏
页数:13
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