Pathway to Construct α-Acyloxy Esters by B(C6F5)3-Catalyzed O-H Insertion of Carboxylic Acids with Sulfoxonium Ylides

被引：2

作者：

Xu, Shuran ^{[1
]}

Zhang, Qingyao ^{[1
]}

Li, Yuanyuan ^{[1
]}

Luo, Cankun ^{[1
]}

Lai, Ruizhi ^{[1
]}

Guo, Li ^{[1
]}

Hai, Li ^{[1
]}

Lv, Guanghui ^{[1
,2
]}

Wu, Yong ^{[1
]}

机构：

[1] Sichuan Univ, West China Sch Pharm, Key Lab Drug Targeting & Drug Delivery Syst, Educ Minist,Dept Med Chem, Chengdu 610041, Sichuan, Peoples R China

[2] Hubei Univ Med, Taihe Hosp, Hubei Prov Clin Res Ctr Umbilical Cord Blood Hemat, Dept Pharm, Shiyan 442000, Hubei, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 21期

关键词：

PHARMACOKINETIC PROPERTIES; ANTIBACTERIAL ACTIVITY; ISOBUTENE; COPOLYMERIZATION; ADDUCTS; BONDS;

D O I：

10.1021/acs.joc.3c01830

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the first example of B-(C6F5)(3)-catalyzed O-H insertion reaction of sulfoxonium ylides and carboxylic acids, achieving efficient construction of diester moieties under metal-free condition. This protocol is characterized by broad substrate tolerance, particularly for various phenylacetic acids, and good compatibility with water/air condition, which is superior to most other methods.

引用

页码：15335 / 15349

页数：15

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