Halide Complexes [(2-Br-5-MePy)2ZnX2] (X = Cl, Br): Structure and Noncovalent Interactions in the Crystal Structure

被引：2
|
作者：
Vershinin, M. A. [1 ]
Novikov, A. S. [2 ,3 ]
Adonin, S. A. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] St Petersburg State Univ, St Petersburg, Russia
[3] Peoples Friendship Univ Russia, Moscow, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2023年 / 49卷 / 05期
关键词：
zinc complexes; N-donor ligands; halogen bonds; crystal structure; quantum chemical calculations; HALOGEN BOND DONOR; VAN-DER-WAALS; DIARYLIODONIUM; 1,4-DIIODOTETRAFLUOROBENZENE; COPPER(II); HYDROGEN; COVALENT; RADII;
D O I：
10.1134/S1070328423700574
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heteroligand complexes [(2-Br-5-MePy)(2)ZnX2] (X = Cl (I), Br (II)) were prepared by the reaction of zinc(II) chloride or bromide with 2-bromo-5-methylpyridine and studied by X-ray diffraction (CCDC nos. 2204966 (I) and 2204967 (II)). The crystals of I and II contain Cl center dot center dot center dot Br and Br center dot center dot center dot Br halogen bonds, which connect the [MX2L2] moieties into supramolecular chains. The energies of these noncovalent interactions were estimated using quantum chemical calculations.
引用
收藏
页码：294 / 298
页数：5
相关论文
共 50 条
  • [31] STRUCTURE AND PROPERTIES OF GD2XC (X = CL, BR, I)
    BAUHOFER, C
    MATTAUSCH, H
    MILLER, GJ
    BAUHOFER, W
    KREMER, RK
    SIMON, A
    JOURNAL OF THE LESS-COMMON METALS, 1990, 167 (01): : 65 - 79
  • [32] STRUCTURE AND LUMINESCENCE OF ME2PHPAUX (X = CL, BR, I)
    WEISSBART, B
    TORONTO, DV
    TINTI, DS
    BALCH, AL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 474 - INOR
  • [33] Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)
    S. A. Adonin
    M. N. Sokolov
    V. P. Fedin
    Journal of Structural Chemistry, 2019, 60 : 1655 - 1659
  • [34] Synthesis, structure, and properties of a new family of mixed-framework chalcohalide semiconductors:: CdSbS2X (X = Cl, Br), CdBiS2X (X = Cl, Br), and CdBiSe2X (X = Br, I)
    Wang, L
    Hung, YC
    Hwu, SJ
    Koo, HJ
    Whangbo, MH
    CHEMISTRY OF MATERIALS, 2006, 18 (05) : 1219 - 1225
  • [35] RELATION BETWEEN STRUCTURES AND SPECTROSCOPIC PROPERTIES OF GROUP-2B METAL [M(CHELATE)X2] COMPLEXES (X=CL,BR,I) - CRYSTAL AND MOLECULAR-STRUCTURE OF [H2NCH2(CH3)2CCH2NH2]MX2 COMPLEXES (M=ZN,X=CL, BR,M=CD, X=BR)
    CARIATI, F
    CIANI, G
    MENABUE, L
    PELLACANI, GC
    RASSU, G
    SIRONI, A
    INORGANIC CHEMISTRY, 1983, 22 (13) : 1897 - 1902
  • [36] Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)
    Adonin, S. A.
    Sokolov, M. N.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (10) : 1655 - 1659
  • [37] Crystal structure of Tl5{[Nb2S4Br8]Br}
    A. L. Gushchin
    M. N. Sokolov
    E. V. Peresypkina
    V. P. Fedin
    Journal of Structural Chemistry, 2008, 49 : 753 - 757
  • [38] Osmium(IV) Halide Complexes with Dimethyl Sulfoxide[H(dmso)2][OsX5(dmso-κO)], X=Cl, Br: Synthesis, Structure, and Properties
    Rudnitskaya, Olga, V
    Dobrokhotova, Ekaterina, V
    Kultyshkina, Ekaterina K.
    Tereshina, Tatiana A.
    Trigub, Alexander L.
    Zubavichus, Yan, V
    Khrustalev, Victor N.
    CHEMISTRYSELECT, 2020, 5 (01): : 330 - 334
  • [39] Crystal structure of Tl5{[Nb2S4Br8]Br}
    Gushchin, A. L.
    Sokolov, M. N.
    Peresypkina, E. V.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (04) : 753 - 757
  • [40] Synthesis, structure and property characterization of a new family of semiconducting mixed-framework chalcohalides: CdSbS2X (X = Cl, Br), CdBiS2X (X = Cl, Br), CdBiSe2X (X = Br, I)
    Wang, L
    Hung, YC
    Hwa, SJ
    Whangbo, MH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2242 - U2243
12345