Halide Complexes [(2-Br-5-MePy)2ZnX2] (X = Cl, Br): Structure and Noncovalent Interactions in the Crystal Structure

被引：2
|
作者：
Vershinin, M. A. [1 ]
Novikov, A. S. [2 ,3 ]
Adonin, S. A. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] St Petersburg State Univ, St Petersburg, Russia
[3] Peoples Friendship Univ Russia, Moscow, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2023年 / 49卷 / 05期
关键词：
zinc complexes; N-donor ligands; halogen bonds; crystal structure; quantum chemical calculations; HALOGEN BOND DONOR; VAN-DER-WAALS; DIARYLIODONIUM; 1,4-DIIODOTETRAFLUOROBENZENE; COPPER(II); HYDROGEN; COVALENT; RADII;
D O I：
10.1134/S1070328423700574
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The heteroligand complexes [(2-Br-5-MePy)(2)ZnX2] (X = Cl (I), Br (II)) were prepared by the reaction of zinc(II) chloride or bromide with 2-bromo-5-methylpyridine and studied by X-ray diffraction (CCDC nos. 2204966 (I) and 2204967 (II)). The crystals of I and II contain Cl center dot center dot center dot Br and Br center dot center dot center dot Br halogen bonds, which connect the [MX2L2] moieties into supramolecular chains. The energies of these noncovalent interactions were estimated using quantum chemical calculations.
引用
收藏
页码：294 / 298
页数：5
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