Bio-Inspired Stimuli-Responsive Ti3C2Tx/PNIPAM Anisotropic Hydrogels for High-Performance Actuators

被引:77
作者
Yan, Qian [1 ]
Ding, Renjie [1 ]
Zheng, Haowen [1 ]
Li, Pengyang [1 ]
Liu, Zonglin [1 ]
Chen, Zhong [1 ]
Xiong, Jinhua [1 ]
Xue, Fuhua [1 ]
Zhao, Xu [1 ]
Peng, Qingyu [1 ]
He, Xiaodong [1 ]
机构
[1] Harbin Inst Technol, Ctr Composite Mat & Struct, Natl Key Lab Sci & Technol Adv Composites Special, Harbin 150080, Peoples R China
关键词
anisotropic hydrogels; hydrogel actuators; MXenes; photothermal conversion; stimuli-responsive; TEMPERATURE;
D O I
10.1002/adfm.202301982
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Near-infrared (NIR) light-responsive hydrogels have the advantages of high precision, remote control and excellent biocompatibility, which are widely used in soft biomimetic actuators. The process by which water molecules diffuse can directly affect the deformation of hydrogel. Therefore, it remains a serious challenge to improve the response speed of hydrogel actuator. Herein, an anisotropic photo-responsive conductive hydrogel is designed by a directional freezing method. Due to the anisotropy of the MXene-based PNIPAM/MXene directional (PMD) hydrogel, its mechanical properties and conductivity are enhanced in a specific direction. At the same time, with the presence of the internal directional channels and the assistance of capillary force, the PMD hydrogel can achieve a volume deswelling of 70% in 2 s under light irradiation, further building a hydrogel actuator with a fast response performance. Additionally, the hydrogel actuator can lift an object 40 times its weight by a distance of 6 mm, realizing the advantages of both rapid responsiveness and high driving strength, which makes the hydrogel actuator have important application significance in remote control, microflow valve, and soft robot.
引用
收藏
页数:12
相关论文
共 45 条
[1]   ON OFF THERMOCONTROL OF SOLUTE TRANSPORT .1. TEMPERATURE-DEPENDENCE OF SWELLING OF N-ISOPROPYLACRYLAMIDE NETWORKS MODIFIED WITH HYDROPHOBIC COMPONENTS IN WATER [J].
BAE, YH ;
OKANO, T ;
KIM, SW .
PHARMACEUTICAL RESEARCH, 1991, 8 (04) :531-537
[2]   Leaf-inspired multiresponsive MXene-based actuator for programmable smart devices [J].
Cai, Guofa ;
Ciou, Jing-Hao ;
Liu, Yizhi ;
Jiang, Yi ;
Lee, Pooi See .
SCIENCE ADVANCES, 2019, 5 (07)
[3]   Multi-scale characterization of surface-crosslinked superabsorbent polymer hydrogel spheres [J].
Chang, Sooho ;
Kim, Minsu ;
Oh, Seunghee ;
Min, Ji Hong ;
Kang, Donyoung ;
Han, Changsun ;
Ahn, Taebin ;
Koh, Won-Gun ;
Lee, Hyungsuk .
POLYMER, 2018, 145 :174-183
[4]   Pristine Titanium Carbide MXene Hydrogel Matrix [J].
Chen, Hongwu ;
Ma, Hongyun ;
Zhang, Panpan ;
Wen, Yeye ;
Qu, Liangti ;
Li, Chun .
ACS NANO, 2020, 14 (08) :10471-10479
[5]   Increased volume responsiveness of macroporous hydrogels [J].
Coukouma, Andrew E. ;
Asher, Sanford A. .
SENSORS AND ACTUATORS B-CHEMICAL, 2018, 255 :2900-2903
[6]  
DING R, 2023, VISUAL COMPUT, DOI DOI 10.1039/D3MH00060E
[7]   Skin inspired multifunctional crumpled Ti3C2Tx MXene/Tissue composite film [J].
Ding, Renjie ;
Zheng, Haowen ;
Zhao, Xu ;
Xue, Fuhua ;
Li, Pengyang ;
Xiong, Jinhua ;
Chen, Zhong ;
Liu, Zonglin ;
Peng, Qingyu ;
He, Xiaodong .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2022, 158
[8]   Saturable Absorption in 2D Ti3C2 MXene Thin Films for Passive Photonic Diodes [J].
Dong, Yongchang ;
Chertopalov, Sergii ;
Maleski, Kathleen ;
Anasori, Babak ;
Hu, Longyu ;
Bhattacharya, Sriparna ;
Rao, Apparao M. ;
Gogotsi, Yury ;
Mochalin, Vadym N. ;
Podila, Ramakrishna .
ADVANCED MATERIALS, 2018, 30 (10)
[9]   Dual-gradient enabled ultrafast biomimetic snapping of hydrogel materials [J].
Fan, Wenxin ;
Shan, Caiyun ;
Guo, Hongyu ;
Sang, Jianwei ;
Wang, Rui ;
Zheng, Ranran ;
Sui, Kunyan ;
Nie, Zhihong .
SCIENCE ADVANCES, 2019, 5 (04)
[10]   Muscle-Inspired MXene Conductive Hydrogels with Anisotropy and Low-Temperature Tolerance for Wearable Flexible Sensors and Arrays [J].
Feng, Yubin ;
Liu, Hou ;
Zhu, Weihang ;
Guan, Lin ;
Yang, Xinting ;
Zvyagin, Andrei, V ;
Zhao, Yue ;
Shen, Chun ;
Yang, Bai ;
Lin, Quan .
ADVANCED FUNCTIONAL MATERIALS, 2021, 31 (46)