共 25 条
Greener rigid polyurethane nanocomposite foams: investigation of physico-mechanical properties formulated with eco-friendly blowing agents
被引:2
作者:

Acharya, Sakti Ranjan
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机构:
Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India
Utkal Univ, Dept Chem, Bhubaneswar 751004, Orissa, India Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India

Palai, Akshaya Kumar
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机构:
Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India

Mohanty, Smita
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机构:
Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India
机构:
[1] Cent Inst Petrochem Engn & Technol CIPET, Sch Adv Res Petrochem, Lab Adv Res Polymer Mat SARP LARPM, Bhubaneswar 751024, Orissa, India
[2] Utkal Univ, Dept Chem, Bhubaneswar 751004, Orissa, India
关键词:
Rigid polyurethane foams (RPUF);
Cyclopentane (CP);
Methyl Formate (MF);
Functionalized MWCNT (f-MWCNT);
And Bio-based polyols;
VEGETABLE-OIL;
CARBON NANOTUBES;
D O I:
10.1007/s10965-022-03343-5
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
In the current investigation, two different grades of bio-based polyols have been used to formulate rigid polyurethane foams (RPUFs). Environment-friendly blowing agents having low ozone-depleting potential like cyclopentane (CP) and methyl formate (MF) were employed to produce greener RPUFs. The prepared foams were evaluated for their chemical structure, cellular structure, free rising density, compressive strength and thermal properties. The formation of characteristic urethane linkage in the foams has been confirmed by Fourier transform infrared (FT-IR) studies. Scanning electron microscopy (SEM) results showed uniform cellular morphology of the RPUF blown with CP. The improved compressive strength of RPUF could be achieved with CP as a blowing agent along with low thermal conductivity. To further enhance the dimensional stability, functionalized multiwall carbon nanotubes (f-MWCNT) have also been introduced into CP-based RPUF and physico-mechanical properties have been investigated.
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