Activated carbon treated with different chemical agents for pertechnetate adsorption

被引:12
作者
Hupian, Marek [1 ]
Galambos, Michal [1 ]
Viglasova, Eva [1 ]
Rosskopfova, Olga [1 ]
Kusumkar, Vipul Vilas [1 ]
Dano, Martin [2 ]
机构
[1] Comenius Univ, Fac Nat Sci, Dept Nucl Chem, Ilkovicova 6, Bratislava 84215, Slovakia
[2] Czech Tech Univ, Fac Nucl Sci & Phys Engn, Dept Nucl Chem, Brehova 7, Prague 11519, Czech Republic
关键词
Pertechnetate; Activated carbon; Chemical activation; Adsorption; ORGANIC FRAMEWORK; REMOVAL; SORPTION; RADIONUCLIDES; WASTE; EQUILIBRIUM; REDUCTION; KINETICS; URANIUM; TC(VII);
D O I
10.1007/s10967-024-09399-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The study investigated the adsorption behaviour of different activated carbon samples for pertechnetate under diverse conditions. Characterizations of A-CF-F and A-CF-Z samples were done using BET, FTIR, XRD, XRF and SEM-EDX methods. In batch experiments, maximum adsorption occured at pH 2, with a swift process and an optimal phase mixing time determined as 1 h for all of the samples. Analyzing experimental data using Langmuir and Freundlich adsorption models revealed coefficients of determination R2 exceeding 90%. The Freundlich isotherm was found to be more suitable for describing the adsorption process.
引用
收藏
页码:1815 / 1829
页数:15
相关论文
共 63 条
[1]   Investigation of uranium (VI) adsorption by polypyrrole [J].
Abdi, S. ;
Nasiri, M. ;
Mesbahi, A. ;
Khani, M. H. .
JOURNAL OF HAZARDOUS MATERIALS, 2017, 332 :132-139
[2]   Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell: Adsorption kinetics, equilibrium and thermodynamic studies [J].
Al-Othman, Z. A. ;
Ali, R. ;
Naushad, Mu. .
CHEMICAL ENGINEERING JOURNAL, 2012, 184 :238-247
[3]   Clay and carbon materials-based engineered barriers for technetium immobilization [J].
Alexey, Makarov ;
Alexey, Safonov ;
Anastasiia, Sitanskaia ;
Konstantin, Martynov ;
Elena, Zakharova ;
Sergey, Kulyukhin .
PROGRESS IN NUCLEAR ENERGY, 2022, 152
[4]  
Alkhatib AJ., 2015, EUR SCI J, V11, P1
[5]   Mechanisms and adsorption capacities of biochar for the removal of organic and inorganic pollutants from industrial wastewater [J].
Ambaye, T. G. ;
Vaccari, M. ;
van Hullebusch, E. D. ;
Amrane, A. ;
Rtimi, S. .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 2021, 18 (10) :3273-3294
[6]   Using granular activated carbon prepared from oil palm shell by ZnCl2 and physical activation for methane adsorption [J].
Arami-Niya, Arash ;
Daud, Wan Mohd Ashri Wan ;
Mjalli, Farouq S. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2010, 89 (02) :197-203
[7]   Zirconium-Based Metal-Organic Framework for Removal of Perrhenate from Water [J].
Banerjee, Debasis ;
Xu, Wenqian ;
Nie, Zimin ;
Johnson, Lewis E. V. ;
Coghlan, Campbell ;
Sushko, Maria L. ;
Kim, Dongsang ;
Schweiger, Michael J. ;
Kruger, Albert A. ;
Doonan, Christian J. ;
Thallapally, Praveen K. .
INORGANIC CHEMISTRY, 2016, 55 (17) :8241-8243
[8]   Review on Activated Carbons by Chemical Activation with FeCl3 [J].
Bedia, Jorge ;
Penas-Garzon, Manuel ;
Gomez-Aviles, Almudena ;
Rodriguez, Juan J. ;
Belver, Carolina .
C-JOURNAL OF CARBON RESEARCH, 2020, 6 (02)
[9]  
Dano M, 2020, THESIS CVUT PRAGUE
[10]   Sorption behaviour of pertechnetate on oxidized and reduced surface of activated carbon [J].
Dano, Martin ;
Viglasova, Eva ;
Galambos, Michal ;
Rajec, Pavol ;
Novak, Ivan .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 314 (03) :2219-2227