Frustrated Lewis pair chemistry of alkynes

被引：12

作者：

Guo, Jing ^{[1
]}

Yan, Maying ^{[1
]}

Stephan, Douglas W. ^{[1
,2
]}

机构：

[1] Ningbo Univ, Inst Drug Discovery Technol, Ningbo, Zhejiang, Peoples R China

[2] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada

来源：

ORGANIC CHEMISTRY FRONTIERS | 2024年 / 11卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

1,1-CARBOBORATION REACTIONS; ADDITION-REACTIONS; TERMINAL ALKYNES; H BOND; ACTIVATION; HYDROGENATION; B(C6F5)(3); REACTIVITY; CYCLIZATION; ALDEHYDE;

D O I：

10.1039/d4qo00217b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The concept of frustrated Lewis pairs (FLPs) has proved to be a general principle for the activation and reactivity of small molecules. In this review, we focus on the chemistry of FLPs with alkynes. We first survey the range of donors and acceptors that are used in stoichiometric reactions with terminal and functionalized alkynes. In the second portion of the review, we discuss advances that exploit FLPs for catalytic reactions and conclude with a perspective on future directions. This review is focused on the chemistry of frustrated Lewis pairs (FLPs) with alkynes and surveys the range of stoichiometric and catalytic reactions enabled by this concept.

引用

页码：2375 / 2396

页数：22

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