Tourmaline as an indicator of ore-forming processes: Evidence from the Laodou gold deposit, Northwest China

A detailed textual and geochemical study of tourmaline is presented to trace fluid evolution and ore genesis of the Laodou gold deposit in West Qinling Orogen, Northwest China. Based on petrographic observations and relationships to gold mineralization, three generations and five types of tourmaline were identified. The pre-ore tourmaline generation (Tur A) occurs as phenocryst replacement within quartz diorite porphyry (Tur A1) and metasomatic filling in hydrothermal breccia (Tur A2). It shows intense oscillatory zoning and variable Mg/(Mg + Fe) ratios (0.30-0.67), implying rapid compositional changes controlled by host-rock composition and fluid-rock interaction. The syn-ore tourmaline generation (Tur B) forms as open-space filling (Tur B1) and peripheral overgrowth (Tur B2) of Tur B1. It occurs in quartz-tourmaline and quartz-stibnite-sphalerite-tourmaline veins. Narrow Mg/(Mg + Fe) range (0.48-0.76), poor chemical zoning and more homogeneous compositions of Tur B reflect a higher fluid flux. The post-ore tourmaline generation (Tur C) occurs as monopolar overgrowths developed at the _ c pole of previous tourmaline within granitoids and hydrothermal veins. This has a composition between dravite and foitite with Mg/(Mg + Fe) from 0.65 to 0.95 and no zoning, which reflect formation under low-temperature conditions. Relatively high Sn, Nb and Ta concentrations, LREE enrichment accompanied by strong positive Eu anomalies of Tur A mostly support a magmatic-hydrothermal origin. Slight LREE enrichment and low abundances of sigma REE of Tur B are caused by progressive input of meteoric waters. Tur C shows relative enrichment in Ba, depletions in V and Ni, and a flat REE pattern with negative Eu anomalies, suggesting a metamorphic source. Boron isotope compositions suggest that boron of Tur A (delta 11B average _ 6.49 %o) is sourced from an I-type melt involved with the Laodou quartz diorite porphyry, while the lighter delta 11B values in paragenetically younger tourmaline (Tur C with delta 11B average _ 9.10 %o) support cooling and a metamorphic input sourced from argillaceous slate of the Lower Permian Daguanshan Group. The variations in textural characteristics, chemical and boron isotope compositions from Tur A to Tur C support a fluid mixing between a magmatic-hydrothermal fluid and meteoric waters leaching metasedimentary rocks. Typical morphology, core -to-rim decrease in Mg/(Mg + Fe), Fe3+Al_1, (XAl)(NaR2+)_1 and (AlO)(R2+OH)_1 vectors, decreasing Na, Ca concentrations and Eu anomalies of tourmaline may record cooling, oxidation and dilution during fluid evolu-tion. This process is possibly caused by fluid mixing and results in gold precipitation. Boron sources, as well as fluid provenance and evolution interpreted by tourmaline provide insight into the Laodou deposit as an intrusion-related gold deposit.