Development of Au@NiO decorated polypyrrole composite for non-Enzymatic electrochemical sensing of cholesterol

被引：12
作者：
Nagarajan, A. [1 ]
Sethuraman, V. [2 ]
Sridhar, T. M. [3 ]
Sasikumar, R. [1 ]
机构：
[1] Univ Madras, Dept Phys Chem, Guindy Campus, Chennai 600025, Tamil Nadu, India
[2] Amara Raja Battery Ltd, Lithium ion Battery Div, New Energy Technol Ctr, Res & Dev, Tirupati 517520, Andhra Pradesh, India
[3] Univ Madras, Dept Analyt Chem, Chennai 600025, India
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2023年 / 120卷
关键词：
Au@NiO; PPy; Cholesterol; Electrochemical sensor; Polypyrrole; Differential pulse voltammetry; CARBON-NANOTUBES; HIGH-PERFORMANCE; ELECTRON-TRANSFER; GLUCOSE; NANOPARTICLES; BIOSENSOR; GRAPHENE; SENSOR; OXIDATION; SYSTEM;
D O I：
10.1016/j.jiec.2022.12.054
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, glassy carbon electrode modified by Au@NiO decorated polypyrrole nanocomposite (Au@NiO/PPy-GCE) was fabricated for sensing of cholesterol by non-enzymatic electrochemical method. The composite was characterized by XRD, XPS and morphological studies were examined using FE-SEM and TEM. The redox properties of cholesterol were investigated by cyclic voltammetry. When differential pulse voltammetry was employed to sense cholesterol, it exhibited a linear range from 1.0 x 10-5 to 1.0 x 10-4 M, with the sensitivity 7.6 mu A mu M-1 cm-2 and detection limit 5.8 x10-7 M. Hence, this compos-ite has excellent practical applications towards the fabrication of commercial sensors.(c) 2023 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：460 / 466
页数：7
相关论文
共 51 条
[21]   Synthesis and characterization of NiO nanoparticles by thermal decomposition of nickel linoleate and their optical properties [J].
Kalam, Abul ;
Al-Sehemi, Abdullah G. ;
Al-Shihri, Ayed S. ;
Du, Gaohui ;
Ahmad, Tokeer .
MATERIALS CHARACTERIZATION, 2012, 68 :77-81
[22]   Fabrication of Au/Ni/NiO heterostructure nanowires by electrochemical deposition and their temperature dependent magnetic properties [J].
Khan, Maaz ;
Rafique, M. Yasir ;
Razaq, Aamir ;
Mir, Amna ;
Karim, Shafqat ;
Anwar, Shahzad ;
Sultana, Ishrat .
JOURNAL OF SOLID STATE CHEMISTRY, 2020, 284
[23]   Enzyme-conjugated ZnO nanocrystals for collisional quenching-based glucose sensing [J].
Kim, Ki-Eun ;
Kim, Tae Geun ;
Sung, Yun-Mo .
CRYSTENGCOMM, 2012, 14 (08) :2859-2865
[24]   Colorimetric Quantification of Glucose and Cholesterol in Human Blood Using a Nanocomposite Entrapping Magnetic Nanoparticles and Oxidases [J].
Kim, Moon Ii ;
Cho, Daeyeon ;
Park, Hyun Gyu .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2015, 15 (10) :7955-7961
[25]   Advances in conductive polymers [J].
Kumar, D ;
Sharma, RC .
EUROPEAN POLYMER JOURNAL, 1998, 34 (08) :1053-1060
[26]   Electrochemical thin film deposition of polypyrrole on different substrates [J].
Li, CM ;
Sun, CQ ;
Chen, W ;
Pan, L .
SURFACE & COATINGS TECHNOLOGY, 2005, 198 (1-3) :474-477
[27]   Reduced Graphene Oxide Electrically Contacted Graphene Sensor for Highly Sensitive Nitric Oxide Detection [J].
Li, Weiwei ;
Geng, Xiumei ;
Guo, Yufen ;
Rong, Jizan ;
Gong, Youpin ;
Wu, Liqiong ;
Zhang, Xuemin ;
Li, Peng ;
Xu, Jianbao ;
Cheng, Guosheng ;
Sun, Mengtao ;
Liu, Liwei .
ACS NANO, 2011, 5 (09) :6955-6961
[28]   Nonenzymatic glucose sensor based on nickel(II)oxide/ordered mesoporous carbon modified glassy carbon electrode [J].
Luo, Liqiang ;
Li, Fang ;
Zhu, Limei ;
Ding, Yaping ;
Zhang, Zhao ;
Deng, Dongmei ;
Lu, Bo .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2013, 102 :307-311
[29]   Determination of total cholesterol in serum by cholesterol esterase and cholesterol oxidase immobilized and co-immobilized on to arylamine glass [J].
Malik, V ;
Pundir, CS .
BIOTECHNOLOGY AND APPLIED BIOCHEMISTRY, 2002, 35 (03) :191-197
[30]   Silica-Polyaniline Based Bienzyme Cholesterol Biosensor: Fabrication and Characterization [J].
Manesh, Kalayil Manian ;
Santhosh, Padmanabhan ;
Gopalan, Anantha Iyengar ;
Lee, Kwang-Pill .
ELECTROANALYSIS, 2010, 22 (20) :2467-2474
123456