Eco-friendly@one-pot-simultaneous oxygen and chlorine intercalation on graphite surface at low-cost

被引：3

作者：

Jemina, I. ^{[1
]}

Pitchaimani, Jayaraman ^{[1
]}

Ramesh, Pugalenthi ^{[2
]}

Mani, N. ^{[3
]}

机构：

[1] Sri Sai Ram Inst Technol, Dept Chem, Chennai 600044, Tamil Nadu, India

[2] Vivekanandha Coll Arts & Sci Women, Dept Chem, Namakkal 637205, Tamil Nadu, India

[3] Sri Sairam Engn Coll, Dept Mech Engn, Chennai 600044, Tamil Nadu, India

来源：

MATERIALS LETTERS | 2024年 / 362卷

关键词：

Green synthesis; Oxidation; Carbon materials; GRAPHENE OXIDE;

D O I：

10.1016/j.matlet.2024.136207

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The production of in -situ chlorinated graphene oxide was accomplished in a single step without the use of hazardous reagent conditions. This eco-friendly method of producing chlorinated graphene oxide was created by combining the potent oxidizer H2SO5 (Piranha) in place of H2SO4 with NaClO4 and m-CPBA. These techniques provide the major advantage of simultaneously intercalating chlorine and oxygen onto the surface of graphite by a one-step synthesis. The oxygen and chloride functionality were confirmed by spectral techniques (P-XRD, HRTEM, XPS, Raman Spectra, FT -IR, and TGA analysis). This is a one -pot synthesis method for generating Cl-GO materials for use in many industries. It is cost-effective, eco-friendly, simple and high scalable. The focus of our present study is on determining the way Cl-GO performs in supercapacitor applications.

引用

页数：4

共 16 条

[1] Honeycomb Carbon: A Review of Graphene
Allen, Matthew J.
Tung, Vincent C.
Kaner, Richard B.
[J]. CHEMICAL REVIEWS, 2010, 110 (01) : 132 - 145
[2] Bonaccorso F, 2010, NAT PHOTONICS, V4, P611, DOI [10.1038/NPHOTON.2010.186, 10.1038/nphoton.2010.186]
[3] Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications
Chen, Da
Feng, Hongbin
Li, Jinghong
[J]. CHEMICAL REVIEWS, 2012, 112 (11) : 6027 - 6053
[4] Erdenedelger G., 2014, J MATER CHEM A, V2, P12526
[5] The rise of graphene
Geim, A. K.
Novoselov, K. S.
[J]. NATURE MATERIALS, 2007, 6 (03) : 183 - 191
[6] Production of chlorine-containing functional group doped graphene powders using Yucel's method as anode materials for Li-ion batteries
Gursu, Hurmus
Guner, Yagmur
Arvas, Melih Besir
Dermenci, Kamil Burak
Savaci, Umut
Gencten, Metin
Turan, Servet
Sahin, Yucel
[J]. RSC ADVANCES, 2021, 11 (63) : 40059 - 40071
[7] PVP-assisted growth of Ni-Co oxide on N-doped reduced graphene oxide with enhanced pseudocapacitive behavior
Huang, Chengxiang
Ding, Yinhui
Hao, Chen
Zhou, Saisai
Wang, Xiaohong
Gao, Haiwen
Zhu, Linli
Wu, Jingbo
[J]. CHEMICAL ENGINEERING JOURNAL, 2019, 378
[8] Park S, 2009, NAT NANOTECHNOL, V4, P217, DOI [10.1038/nnano.2009.58, 10.1038/NNANO.2009.58]
[9] A facile synthesis of hydroxyl functionalized graphene oxide as an electrode material for energy storage devices
Ramesh, P.
Sambathkumar, S.
Jagatheesan, R.
Kumar, S. Vasanth
[J]. MATERIALS LETTERS, 2019, 256
[10] Green approach for the synthesis of monolayer reduced graphene oxide: one-step protocol with simultaneous iodination and reduction
Ramesh, Pugalenthi
Kalicharan, A. Alvin
Pitchaimani, Jayaraman
Koutavarapu, Ravindranadh
[J]. NEW JOURNAL OF CHEMISTRY, 2023, 47 (10) : 4609 - 4613

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