A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium

被引：8
|
作者：
Fernandez-Buenestado, Marta
Somerville, Rosie J.
Lopez-Serrano, Joaquin [1 ]
Campos, Jesus [1 ]
机构：
[1] Univ Seville, Dept Quim Inorgan, Inst Invest Quim IIQ, Ave Americo Vespucio 49, Seville 41092, Spain
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 57期
基金：
欧洲研究理事会;
关键词：
CATALYTIC-HYDROGENATION; COMPLEXES; BIS(SILYLENE); NICKEL;
D O I：
10.1039/d3cc02447d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an 'NHC-type' Ge ligand. Its bonding is substantiated by computational studies and we have demonstrated its use for the catalytic dehydrogenation of formic acid, highlighting the potential of this underdeveloped type of ligand.
引用
收藏
页码：8826 / 8829
页数：4
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