Study on Self-Humidification in PEMFC with Crossed Flow Channels and an Ultra-Thin Membrane

被引:4
作者
Wang, Chenlong [1 ,2 ]
Chen, Xiaosong [1 ,2 ]
Xiang, Xin [1 ,2 ]
Zhang, Heng [1 ,2 ]
Huang, Zhiping [1 ,2 ]
Huang, Xinhao [1 ,2 ]
Zhan, Zhigang [1 ,2 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[2] Hubei Key Lab Fuel Cells, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
PEMFC; 3D model; self-humidification; crossed channel; ultra-thin membrane; operating condition; water distribution; cell performance; FUEL-CELL SYSTEM; PERFORMANCE; HUMIDITY; NANOPARTICLES; DURABILITY; LAYER;
D O I
10.3390/polym15234589
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, a 3D model of a proton exchange membrane fuel cell (PEMFC) with crossed channels and an ultra-thin membrane is developed to investigate the feasibility of self-humidification; experiments utilizing a PEMFC stack with identical configurations are conducted to validate the simulation results and further investigate the effects of various operating conditions (OCs) on self-humidification. The results indicate that the crossed flow channel leads to enhanced uniformity of water distribution, resulting in improved cell performance under low/no humidification conditions. External humidifiers for the anode can be removed since the performance difference is negligible (<= 3%) between RHa = 0% and 100%. Self-humidification can be achieved in the stack at 90 degrees C or below with an appropriate back pressure among 100-200 kPa. As the current density increases, there is a gradual convergence and crossing of the voltage at low RH with that at high RH, and the crossover points are observed at 60-80 degrees C with suitable pressure when successful self-humidification is achieved. Below the current density of the point, the stack's performance is inferior at lower RH due to membrane unsaturation, and conversely, the performance is inferior at higher RH due to flooding; this current density decreases with higher pressure and lower temperature.
引用
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页数:19
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