Study on Self-Humidification in PEMFC with Crossed Flow Channels and an Ultra-Thin Membrane

被引:4
作者
Wang, Chenlong [1 ,2 ]
Chen, Xiaosong [1 ,2 ]
Xiang, Xin [1 ,2 ]
Zhang, Heng [1 ,2 ]
Huang, Zhiping [1 ,2 ]
Huang, Xinhao [1 ,2 ]
Zhan, Zhigang [1 ,2 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[2] Hubei Key Lab Fuel Cells, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
PEMFC; 3D model; self-humidification; crossed channel; ultra-thin membrane; operating condition; water distribution; cell performance; FUEL-CELL SYSTEM; PERFORMANCE; HUMIDITY; NANOPARTICLES; DURABILITY; LAYER;
D O I
10.3390/polym15234589
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, a 3D model of a proton exchange membrane fuel cell (PEMFC) with crossed channels and an ultra-thin membrane is developed to investigate the feasibility of self-humidification; experiments utilizing a PEMFC stack with identical configurations are conducted to validate the simulation results and further investigate the effects of various operating conditions (OCs) on self-humidification. The results indicate that the crossed flow channel leads to enhanced uniformity of water distribution, resulting in improved cell performance under low/no humidification conditions. External humidifiers for the anode can be removed since the performance difference is negligible (<= 3%) between RHa = 0% and 100%. Self-humidification can be achieved in the stack at 90 degrees C or below with an appropriate back pressure among 100-200 kPa. As the current density increases, there is a gradual convergence and crossing of the voltage at low RH with that at high RH, and the crossover points are observed at 60-80 degrees C with suitable pressure when successful self-humidification is achieved. Below the current density of the point, the stack's performance is inferior at lower RH due to membrane unsaturation, and conversely, the performance is inferior at higher RH due to flooding; this current density decreases with higher pressure and lower temperature.
引用
收藏
页数:19
相关论文
共 50 条
  • [1] Self-humidified operation of a PEM fuel cell using a novel silica composite coating method
    Angayarkanni, R.
    Ganesan, Aristatil
    Dhelipan, M.
    Karthikeyan, S.
    Mani, N.
    Thiyagarajan, P.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (07) : 4827 - 4837
  • [2] Comparative performance evaluation of self-humidifying PEMFCs with short-side-chain and long-side-chain membranes under various operating conditions
    Cha, Dowon
    Jeon, Seung Won
    Yang, Wonseok
    Kim, Dongwoo
    Kim, Yongchan
    [J]. ENERGY, 2018, 150 : 320 - 328
  • [3] Humidification strategy for polymer electrolyte membrane fuel cells - A review
    Chang, Yafei
    Qin, Yanzhou
    Yin, Yan
    Zhang, Junfeng
    Li, Xianguo
    [J]. APPLIED ENERGY, 2018, 230 : 643 - 662
  • [4] Methodology for PEMFC CFD Simulation Including the Effect of Porous Parts Compression
    Corda, Giuseppe
    Fontanesi, Stefano
    d'Adamo, Alessandro
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (32) : 14658 - 14673
  • [5] A review of proton exchange membranes based on protic ionic liquid/polymer blends for polymer electrolyte membrane fuel cells
    Elwan, Hosni Ahmed
    Mamlouk, Mohamed
    Scott, Keith
    [J]. JOURNAL OF POWER SOURCES, 2021, 484
  • [6] Characteristics of PEMFC operating at high current density with low external humidification
    Fan, Linhao
    Zhang, Guobin
    Jiao, Kui
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2017, 150 : 763 - 774
  • [7] [何晓波 He Xiaobo], 2017, [工程热物理学报, Journal of Engineering Thermophysics], V38, P1994
  • [8] Self-Humidifying Membrane for High-Performance Fuel Cells Operating at Harsh Conditions: Heterojunction of Proton and Anion Exchange Membranes Composed of Acceptor-Doped SnP2O7 Composites
    Heo, Pilwon
    Kim, Mijeong
    Ko, Hansol
    Nam, Sang Yong
    Kim, Kihyun
    [J]. MEMBRANES, 2021, 11 (10)
  • [9] Enhanced low-humidity performance of proton-exchange membrane fuel cell by introducing hydrophilic CNTs in membrane electrode assembly
    Hou, Sanying
    Wang, Hongqing
    Ren, Jianwei
    Yao, Chen
    Shi, Lang
    Liao, Shijun
    [J]. PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2022, 32 (02) : 150 - 156
  • [10] A self-humidifying proton exchange membrane embedded with phosphonic acid-functionalized mesoporous silica nanoparticles that has excellent dispersion and water retention
    Huang, Henghui
    Xu, Shaoyi
    Zhang, Li
    Fan, Jiantao
    Li, Hui
    Wang, Haijiang
    [J]. SUSTAINABLE ENERGY & FUELS, 2021, 5 (01) : 230 - 245