Unravelling the influence of interfacial tailoring in metal-organic framework-derived ultrathin sheets of Co2P/Cu3P for high- performance hybrid supercapacitor

被引:28
作者
Kale, A. M. [1 ]
Velayutham, R. [1 ]
Savariraj, A. D. [1 ]
Demir, M. [2 ,3 ]
Kim, B. C. [1 ]
机构
[1] Sunchon Natl Univ, Dept Adv Components & Mat Engn, 255, Jungang ro, Sunchon 57922, South Korea
[2] Osmaniye Korkut Ata Univ, Dept Chem Engn, TR-80000 Osmaniye, Turkiye
[3] Mat Inst, TUBITAK Marmara Res Ctr, TR-41470 Gebze, Turkiye
基金
新加坡国家研究基金会;
关键词
ZIF-67; Bimetallic phosphides; Phosphorization; Battery type electrode; Hybrid supercapacitor; NI FOAM; WATER; PHOSPHIDES; HYDROGEN; COP; HETEROSTRUCTURES; SUPERCAPATTERY; ELECTRODES; NANOSHEETS; PHOSPHATE;
D O I
10.1016/j.mtsust.2023.100335
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Metal-organic frameworks (MOFs) with porous and diverse structures have created to devote research for MOF based materials for energy storage application, but their inadequate conductivity and sturdiness impede their realistic progress. MOF-derived transition metal phosphides (TMPs) materials could maintain the architectural diversity and porosity of MOFs, as well as, boost their electrical conductivity and durability. Herein, for the first time, we unravel the influence of interfacial tailoring in MOF tem-plated cobalt copper phosphide (CoCuP) composite as electrode material for supercapacitor with battery -type behavior. The as-synthesized MOF-derived cobalt copper phosphide electrode (CoCuP@400) pre-pared at optimum 400 degrees C phosphorization temperature exhibits outstanding electrochemical perfor-mance by delivering a specific capacity (Csp) of 549 C/g (152.5-mAh/g) at a specific current of 1 A/g in aqueous electrolyte (6 M KOH). Additionally, by applying CoCuP@400 as a positive electrode (energy source) and lima bean shell-derived oxygen, nitrogen, and sulfur-enriched porous carbon (O, N, S@AC) as a negative electrode (power source), a hybrid supercapacitor device fabricated, which unveiled a widespread working potential window of 1.5 V. In addition, the hybrid supercapacitor device revealed a specific capacity of 38-mAh/g with a maximum specific energy (Esp) of 37.3 Wh/kg and a maximum specific power (Psp) of 12308.8 W/kg as well as exceptional cyclic stability over 10,000 uninterrupted galvanostatic charge/discharge cycles with 89% of initial capacity retention. As a result, after synthetic phosphorization technique for synthesizing electrode materials offers a new avenue for using battery -type supercapacitors. (c) 2023 Elsevier Ltd. All rights reserved.
引用
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页数:16
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