Vapor-Liquid Equilibrium Phase Behavior of Binary Systems of Carbon Dioxide with Eugenol or Guaiacol

被引：2
|
作者：
Tiwikrama, Ardila Hayu [1 ]
Khudaida, Salal Hasan [1 ]
Long, Ching-Yu [1 ]
机构：
[1] Natl Taipei Univ Technol, Chem Engn & Biotechnol Dept, Taipei 10608, Taiwan
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2023年 / 68卷 / 12期
关键词：
PHENOLIC-COMPOUNDS; MIXTURES; EXTRACTION; ETHANOL; SOLUBILITY; BOUNDARIES; OIL;
D O I：
10.1021/acs.jced.3c00370
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The vapor-liquid equilibrium (VLE) phase boundary data for the binary systems consisting of carbon dioxide + eugenol and carbon dioxide + guaiacol were determined experimentally in the temperature range from 313.15 to 373.15 K and at pressures up to 24 MPa. The phase transition over the entire composition range was observed by using a variable-volume and visual phase equilibrium analyzer. From the VLE phase boundary data, K-values and critical points for VLE have been estimated. The present study involved the correlation of the recently obtained VLE data with two equations of state, namely, the Soave-Redlich-Kwong and the Peng-Robinson equations. These equations were modified to incorporate the two-parameter van der Waals one-fluid mixing rule. Overall, the average absolute pressure deviations are lower than 3%.
引用
收藏
页码：3298 / 3305
页数：8
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