Photocatalytic reactions of fluoroalkyl iodides with alkenes

被引：8

作者：

Chernov, G. I. ^{[1
]}

Levin, V. V. ^{[2
]}

Dilman, A. D. ^{[2
]}

机构：

[1] Tomsk Polytech Univ, Res Sch Chem & Appl Biomed Sci, 30 prosp Lenina, Tomsk 634050, Russia

[2] Russian Acad Scienses, N D Zelinsky Inst Organ Chem, 47 Leninsky prosp, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 01期

关键词：

organofluorine chemistry; fluoroalkyl iodides; alkenes; photocatalysis; radicals; TRANSFER RADICAL-ADDITION; PHOTOREDOX CATALYSIS; PERFLUOROALKYL IODIDES; LIGHT; TRIFLUOROMETHYLATION; GENERATION; IODOPERFLUOROALKYLATION; ORGANOFLUORINE; COMPLEXES; ALKYNES;

D O I：

10.1007/s11172-023-3714-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluoroalkyl iodides are convenient sources of fluoroalkyl radicals under photocatalytic conditions. After the addition of a fluorine radical to a double bond, the resulting radical can react in several directions, including abstraction of an iodine atom from the starting iodide, abstraction of a hydrogen atom from a reducing agent, intramolecular interception by an aromatic system, and one-electron oxidation. These reactions make it possible to obtain a wide range of organofluorine compounds. The review summarizes data for the last five years.

引用

页码：61 / 72

页数：12

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