Photocatalytic reactions of fluoroalkyl iodides with alkenes

被引：8
作者：
Chernov, G. I. [1 ]
Levin, V. V. [2 ]
Dilman, A. D. [2 ]
机构：
[1] Tomsk Polytech Univ, Res Sch Chem & Appl Biomed Sci, 30 prosp Lenina, Tomsk 634050, Russia
[2] Russian Acad Scienses, N D Zelinsky Inst Organ Chem, 47 Leninsky prosp, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 01期
关键词：
organofluorine chemistry; fluoroalkyl iodides; alkenes; photocatalysis; radicals; TRANSFER RADICAL-ADDITION; PHOTOREDOX CATALYSIS; PERFLUOROALKYL IODIDES; LIGHT; TRIFLUOROMETHYLATION; GENERATION; IODOPERFLUOROALKYLATION; ORGANOFLUORINE; COMPLEXES; ALKYNES;
D O I：
10.1007/s11172-023-3714-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fluoroalkyl iodides are convenient sources of fluoroalkyl radicals under photocatalytic conditions. After the addition of a fluorine radical to a double bond, the resulting radical can react in several directions, including abstraction of an iodine atom from the starting iodide, abstraction of a hydrogen atom from a reducing agent, intramolecular interception by an aromatic system, and one-electron oxidation. These reactions make it possible to obtain a wide range of organofluorine compounds. The review summarizes data for the last five years.
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收藏
页码：61 / 72
页数：12
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