Fullerene trigged energy storage and photocatalytic ability of La2O3-ZnO@C60 core-shell nanocomposite

被引:47
作者
Sardar, Sonia [1 ]
Munawar, Tauseef [1 ]
Mukhtar, Faisal [1 ]
Nadeem, Muhammad Shahid [1 ]
Khan, Shoukat Alim [2 ]
Koc, Muammer [2 ]
Manzoor, Sumaira [3 ]
Ashiq, Muhammad Naeem [3 ]
Iqbal, Faisal [1 ]
机构
[1] Islamia Univ Bahawalpur, Inst Phys, Bahawalpur 63100, Pakistan
[2] Hamad Bin Khalifa Univ, Qatar Fdn, Coll Sci & Engn, Div Sustainable Dev, Doha, Qatar
[3] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2023年 / 288卷
关键词
Fullerene; Core; -shell; Oxidation states; Pseudocapacitive; Charge transportation; Hazardous dyes; REDUCED GRAPHENE OXIDE; ELECTRODE MATERIALS; SUPERCAPACITIVE PERFORMANCE; OPTICAL-PROPERTIES; ZNO NANOPARTICLES; FACILE SYNTHESIS; DEGRADATION; EFFICIENT; DEVICE; STATE;
D O I
10.1016/j.mseb.2022.116151
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fullerene (C60)-based carbon materials are attracting the attention of researchers because of their large surface area, three-dimensional structure, tunable architectures, and high chemical stability. In this study, the core-shell nanocomposite of lanthanum oxide (La2O3), zinc oxide (ZnO), and C60 was prepared via the solution method. Transmission electron microscope (TEM) images confirmed the development of core-shell with La2O3-ZnO (core) and C60 (shell). The photodegradation test against methylene blue (MB) dye showed complete degradation after 40 min. The electrochemical performance of La2O3-ZnO@C60 exposed large pseudo-capacitance, reversible Faradic charge-storage mechanism, and outstanding cyclic stability (93 % retention after 1000th cycle) and exhibited superior specific capacitance of 2135 F/g at 0.05 A/g with a remarkable energy density of 47.44 Wh/ kg at the power density of 2.26 KW/kg. Thus, La2O3-ZnO@C60 displayed dual functions, such as energy storage materials for next-generation supercapacitor electrodes and an efficient photocatalyst.
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页数:16
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