Co-pyrolysis of textile dyeing sludge/litchi shell and CaO: Immobilization of heavy metals and the analysis of the mechanism

被引:9
作者
Li, Danni [1 ,2 ,3 ]
Shan, Rui [2 ,3 ]
Gu, Jing [2 ,3 ]
Zhang, Yuyuan [6 ]
Zeng, Xianhai [1 ,4 ,5 ]
Lin, Lu [1 ,4 ,5 ]
Yuan, Haoran [1 ,2 ,3 ,4 ,5 ,7 ]
Chen, Yong [1 ,2 ,3 ,4 ,5 ]
机构
[1] Xiamen Univ, Coll Energy, Xiamen 361102, Peoples R China
[2] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
[3] CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
[4] Xiamen Univ, Fujian Engn & Res Ctr Clean & High valued Technol, Xiamen 361102, Peoples R China
[5] Xiamen Univ, Xiamen Key Lab High valued Utilizat Biomass, Xiamen 361102, Peoples R China
[6] Foshan Univ, Sch Mat Sci & Hydrogen Energy, Foshan 528000, Guangdong, Peoples R China
[7] Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
关键词
Co-pyrolysis; Textile dyeing sludge; Litchi shell; Biochar; CaO activation; SEWAGE-SLUDGE; RISK-EVALUATION; BIOCHAR; BIOMASS; STABILIZATION; TEMPERATURE;
D O I
10.1016/j.wasman.2023.09.024
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
To relieve the secondary contamination of heavy metals (HMs), the synergistic effect of co-pyrolysis of textile dyeing sludge (DS)/litchi shell (LS) and CaO on the migration of HMs was demonstrated in this study. The proportions of Cu, Zn, Cr, Mn, and Ni in the F4 fraction increased to 75%, 55%, 100%, 50%, and 62% at the suitable CaO dosages. When 10% CaO was added, the RI value of DLC-10% was reduced to 7.89, indicating low environmental risk. The characterizations of the physicochemical properties of biochar provided support for the HMs immobilization mechanism. HMs combined with inorganic minerals or functional groups to form new stable HMs crystalline minerals and complexes to achieve immobilization of HMs. The pH value and pore structure also play an important role in improving the immobilization performance of HMs. In conclusion, the results provided a new direction for the subsequent harmless treatment of HMs-enriched waste.
引用
收藏
页码:382 / 392
页数:11
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