Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH2PO3H2)2 as a catalyst

被引：5

作者：

Babaee, Saeed ^{[1
]}

Sepehrmansourie, Hassan ^{[1
]}

Zarei, Mahmoud ^{[2
]}

Zolfigol, Mohammad Ali ^{[1
]}

Hosseinifard, Mojtaba ^{[3
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, Hamadan 6517838683, Iran

[2] Univ Qom, Fac Sci, Dept Chem, Qom 37185359, Iran

[3] Mat & Energy Res Ctr, Dept Energy, POB 31787-316, Karaj, Iran

来源：

RSC ADVANCES | 2023年 / 13卷 / 32期

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; BIOLOGICAL-BASED GLYCOLURIL; PHOSPHORUS-ACID TAGS; EFFICIENT CATALYST; MOFS; COMPLEXES; CRYSTAL;

D O I：

10.1039/d3ra03438k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The anomeric effect highlights the significant influence of the functional group and reaction conditions on oxidation-reduction. This article successfully investigates the anomeric effect in the synthesis of picolinate and picolinic acid derivatives through a multi-component reaction involving 2-oxopropanoic acid or ethyl 2-oxopropanoate, ammonium acetate, malononitrile, and various aldehydes. To facilitate this process, we employed UiO-66(Zr)-N(CH2PO3H2)(2) as a novel nanoporous heterogeneous catalyst. The inclusion of phosphorous acid tags on the UiO-66(Zr)-N(CH2PO3H2)(2) offers the potential for synthesizing picolinates at ambient temperature.

引用

页码：22503 / 22511

页数：9

共 69 条

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