Synthesis of picolinates via a cooperative vinylogous anomeric-based oxidation using UiO-66(Zr)-N(CH2PO3H2)2 as a catalyst

被引：5
作者：
Babaee, Saeed [1 ]
Sepehrmansourie, Hassan [1 ]
Zarei, Mahmoud [2 ]
Zolfigol, Mohammad Ali [1 ]
Hosseinifard, Mojtaba [3 ]
机构：
[1] Bu Ali Sina Univ, Fac Chem, Dept Organ Chem, Hamadan 6517838683, Iran
[2] Univ Qom, Fac Sci, Dept Chem, Qom 37185359, Iran
[3] Mat & Energy Res Ctr, Dept Energy, POB 31787-316, Karaj, Iran
来源：
RSC ADVANCES | 2023年 / 13卷 / 32期
基金：
美国国家科学基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; BIOLOGICAL-BASED GLYCOLURIL; PHOSPHORUS-ACID TAGS; EFFICIENT CATALYST; MOFS; COMPLEXES; CRYSTAL;
D O I：
10.1039/d3ra03438k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The anomeric effect highlights the significant influence of the functional group and reaction conditions on oxidation-reduction. This article successfully investigates the anomeric effect in the synthesis of picolinate and picolinic acid derivatives through a multi-component reaction involving 2-oxopropanoic acid or ethyl 2-oxopropanoate, ammonium acetate, malononitrile, and various aldehydes. To facilitate this process, we employed UiO-66(Zr)-N(CH2PO3H2)(2) as a novel nanoporous heterogeneous catalyst. The inclusion of phosphorous acid tags on the UiO-66(Zr)-N(CH2PO3H2)(2) offers the potential for synthesizing picolinates at ambient temperature.
引用
收藏
页码：22503 / 22511
页数：9
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