3D Printing photo-induced lignin nanotubes/polyurethane shape memory composite

被引：25

作者：

Wang, Feng ^{[1
]}

Jiang, Man ^{[1
]}

Pan, Yu ^{[1
]}

Lu, Yuan ^{[1
]}

Xu, Wangjie ^{[1
]}

Zhou, Yufan ^{[1
]}

机构：

[1] Southwest Jiaotong Univ, Sch Mat Sci & Engn, Key Lab Adv Technol Mat, Minist Educ, Chengdu 610031, Peoples R China

来源：

POLYMER TESTING | 2023年 / 119卷

关键词：

3D Printing; Shape memory polymer composite; Shape memory polyurethane; Lignin nanotubes; Photo-induced shape recovery; MOLECULAR-WEIGHT; POLYURETHANE; ELASTOMERS; PYROLYSIS; CELLULOSE; STRENGTH; BEHAVIOR; ROBUST; FILMS;

D O I：

10.1016/j.polymertesting.2023.107934

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The excellent flexibility, biocompatibility, and shape memory properties of polyurethane (PU) have attracted great attention to fabricate devices for application in the fields of electronics and biomedical, etc. However, it still consists a challenge to fabricate shape memory polymer (SMP) materials with complicated shapes in response to remote stimuli precisely and instantly. In this paper, we achieved ultraviolet light responsive SMP composites by direct ink writing (DIW) 3D printing shape memory polyurethane (SMPU) with introduction of the laboratory prepared lignin nanotube (LNT) as UV absorbent. We prepared lignin nanotube with uniform morphology by dissolving and then controllable molecular assembling way during dialysis in deionized water. The 3D printed SMP composite of PU/LNT was found to reach the shape recovery rate of 99% under UV radiation (370 nm) for 15 min. In addition, the tensile strength of the 3D printed SMP composite of PU/LNT is increased to 16.4 MPa, which is 131% higher than that of the pristine PU (7.11 MPa). It is worth noting that the glass transition temperature (Tg) of the 3D printed SMP composite of PU/LNT changed steadily from 47 degrees C to 33 degrees C by increasing the LNT content to 9%, which endows the composites with much wider application feasibility. The exploration on photo responsive 3D printed SMP composites with accurate shape recovery rate provides new candidates to improve the development of biomaterials and intelligent robots.

引用

页数：12

共 72 条

[11]

Du W., 2020, COMPOS PART B-ENG, P195

[12] Properties and chemical modifications of lignin: Towards lignin-based nanomaterials for biomedical applications [J].