Facile modification of phosphole-based aggregation-induced emission luminogens with sulfonyl isocyanates

被引：8

作者：

Koenig, Nils ^{[1
]}

Godinez-Loyola, Yokari ^{[2
,3
]}

Yang Fangshun ^{[4
]}

Laube, Christian ^{[4
]}

Laue, Michael ^{[5
]}

Loennecke, Peter ^{[1
]}

Strassert, Cristian A. ^{[2
,3
]}

Hey-Hawkins, Evamarie ^{[1
]}

机构：

[1] Univ Leipzig, Inst Inorgan Chem, Fac Chem & Mineral, Johannisallee 29, D-04103 Leipzig, Germany

[2] Westfalische Wilhelms Univ Munster, Inst Anorgan & Analyt Chem, CiMiC, SoN, Heisenbergstr 11, D-48149 Munster, Germany

[3] Westfalische Wilhelms Univ Munster, CeNTech, Heisenbergstr 11, D-48149 Munster, Germany

[4] Leibniz Inst Oberflachenmodifizierung eV, Permoserstr 15, D-04318 Leipzig, Germany

[5] Univ Leipzig, Inst Organ Chem, Fac Chem & Mineral, Johannisallee 29, D-04103 Leipzig, Germany

来源：

CHEMICAL SCIENCE | 2023年 / 14卷 / 09期

关键词：

CARRIER TRANSPORT-PROPERTIES; ELECTRONIC-PROPERTIES; CHEMISTRY; TETRAPHENYLETHENE; AROMATICITY; DERIVATIVES; FABRICATION; COMPLEXES; MOLECULES; CRYSTAL;

D O I：

10.1039/d3sc00308f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphole oxides undergo a highly chemoselective reaction with sulfonyl isocyanates forming sulfonylimino phospholes in high yields. This facile modification proved to be a powerful tool for obtaining new phosphole-based aggregation-induced emission (AIE) luminogens with high fluorescence quantum yields in the solid state. Changing the chemical environment of the phosphorus atom of the phosphole framework results in a significant shift of the fluorescence maximum to longer wavelengths.

引用

页码：2267 / 2274

页数：9

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