The Application of Ru- Containing Catalysts in the Reductive Processing of Lignin and Lignocellulosic Biomass (Review)

被引:0
作者
Sychev, Valentin V. [1 ]
Taran, Oxana P.
Kuznetsov, Boris N.
机构
[1] RAS, Inst Chem & Chem Technol, Krasnoyarsk Sci Ctr SB, Fed Res Ctr, Krasnoyarsk, Russia
来源
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2023年 / 16卷 / 02期
基金
俄罗斯基础研究基金会;
关键词
ruthenium catalysts; supports; modification; lignin; depolymerization; lignocellulose; reductive fractionation; phenolic products; GAMMA-VALEROLACTONE; PHASE HYDROGENATION; HYDROGENOLYSIS; FRACTIONATION; WATER; RUTHENIUM; DEPOLYMERIZATION; CONVERSION; PLATFORM;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper presents the latest significant advances in the Ru-containing catalysts application in the reductive processing of lignin and lignocellulosic biomass. The features of the catalytic action of Ru-catalysts in aqueous and water-alcohol media are also considered in comparison with other platinum group metals. The performance of various Ru- based catalytic systems in the processes of lignin depolymerization and processing of lignocellulosic biomass is compared. By modifying and designing supports to provide them acidic properties, a mesoporous structure promoting good reagents transport, and improved distribution of Ru nanoparticles, the efficiency of ruthenium catalysts can be significantly improved. Ru- based catalysts are the most efficient in the processes of reductive processing of lignocellulosic biomass and lignin in aqueous media compared to other platinum group metals.
引用
收藏
页码:202 / 215
页数:14
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