Fabrication of Piezoelectric ZnO Nanowires on Laser Textured Copper Substrate to Enhance Catalytic Properties

In this work, 3D periodic "grid-type" CuO/Cu2O layers were fabricated on a copper sheet using laser processing techniques, and the laser processing parameters were optimized for favorable ZnO nanowire growth. It was found that ZnO nanowires could be successfully prepared to form a CuO-Cu2O-ZnO heterojunction structure without an extra catalyst or seed layer coating, which could be attributed to the copper oxide active sites induced via laser texturing. ZnO nanowires on laser textured "grid-type" copper substrates demonstrated an effective piezocatalytic performance with different morphologies and the generation of abundant reactive oxygen species in the CuO-Cu2O-ZnO catalytic system, providing a fundamental mechanism for the degradation of organic dye in water. This simple and low-cost method could provide a useful guide for the large-scale efficient and versatile synthesis of immobilized piezoelectric catalysts.