Identification of Secondary Metabolites from the Mangrove-Endophyte Lasiodiplodia iranensis F0619 by UPLC-ESI-MS/MS

被引:2
作者
Gomez, Lizbeth M. Delgado [1 ]
Torres-Mendoza, Daniel [1 ,2 ,3 ]
Hernandez-Torres, Kathleen [1 ,4 ]
Ortega, Humberto E. [1 ,2 ]
Cubilla-Rios, Luis [1 ,2 ]
机构
[1] Univ Panama, Fac Ciencias Nat Exactas & Tecnol, Lab Bioorgan Trop, Panama City 0824, Panama
[2] Univ Panama, Fac Ciencias Nat Exactas & Tecnol, Dept Quim Organ, Panama City 0824, Panama
[3] Univ Panama, Vicerrectoria Invest & Postgrad, Panama City 0824, Panama
[4] Univ Panama, Programa Maestria Microbiol Ambiental, Vicerrectoria Invest & Postgrad, Panama City 0824, Panama
关键词
Lasiodiplodia iranensis; jasmonates; mangrove-endophytes; MS/MS fragmentation analysis; MASS-SPECTROMETRY; JASMONIC ACID; FRAGMENTATION; THEOBROMAE; PHYLOGENY; PEPTIDE;
D O I
10.3390/metabo13080912
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Lasiodiplodia is a widely distributed fungal genus, frequently found in tropical and subtropical regions where it can cause disease in important crops. It represents a promising source of active secondary metabolites with uses in chemical, pharmaceutical, and agrochemical processes. In this study, the strain Lasiodiplodia iranensis F0619 was isolated from the mangrove Avicennia ger-minans, collected from Sarigua National Park in the Republic of Panama. Fractions of crude extract were analyzed by UPLC-ESI-MS/MS, and five compounds, previously reported from Lasiodiplodia genus were identified, including 11,12-didehydro-7-iso-jasmonic acid (1), 4,5-didehydro-7-iso-jasmonic acid (2), cyclo-(L-Leu-L-Pro) (3), jasmonate-threonine (4), and abscisic acid (5). We describe and analyze their MS/MS fragmentation patterns to confirm the compounds 'chemical structures.
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页数:15
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