Robust Ruthenium Phosphide Catalyst for Hydrogenation of Sulfur- Containing Nitroarenes

被引：0

作者：

Ishikawa, Hiroya ^{[1
]}

Nakatani, Naoki ^{[2
]}

Yamaguchi, Sho ^{[1
]}

Mizugaki, Tomoo ^{[1
,3
]}

Mitsudome, Takato ^{[1
,4
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Tokyo Metropolitan Univ, Fac & Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan

[3] Osaka Univ, Inst Open & Transdisciplinary Res Initiat OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan

[4] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3330012, Japan

来源：

ACS CATALYSIS | 2023年

关键词：

hydrogenation; heterogeneous catalyst; phosphide; ruthenium; nitroarene; organosulfur compound; SELECTIVE HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; FUNCTIONALIZED NITROARENES; NITRO-COMPOUNDS; REDUCTION; NITROBENZENE; ADSORPTION; SURFACES; DESIGN;

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Development of robust metal catalysts for the hydrogenation of sulfur-containing nitroarenes is challenging because the sulfur atom strongly poisons the active metal sites of the catalyst. We herein report that ruthenium phosphide nanoparticles (Ru2P/SiO2) act as a highly active and robust catalyst for the hydrogenation of sulfur-containing nitroarenes, with 34 times higher activity than that obtained with Ru nanoparticles. Various sulfurcontaining nitroarenes were hydrogenated under 1 bar of H2 and the corresponding anilines, including some important pharmaceutical intermediates, were obtained in high yields. The study results revealed that the electronic and geometrical effects of P surrounding Ru species in Ru2P/SiO2 are crucial to boost the activity and durability against sulfur poisoning.

引用

页码：5744 / 5751

页数：8

共 50 条

[31] A Reusable Co Catalyst for the Selective Hydrogenation of Functionalized Nitroarenes and the Direct Synthesis of Imines and Benzimidazoles from Nitroarenes and Aldehydes [J].

Schwob, Tobias ;

Kempe, Rhett .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (48) :15175-15179

[32] Fabrication of magnetically separable ruthenium nanoparticles decorated on channelled silica microspheres: Efficient catalysts for chemoselective hydrogenation of nitroarenes [J].

Kalita, Gauravjyoti D. ;

Das, Manash R. ;

Das, Pankaj .

DALTON TRANSACTIONS, 2021, 50 (38) :13483-13496

[33] Rational Design of Supported Metal Catalysts for Selective Hydrogenation of Sulfur-Containing Compounds [J].

Chen, Haitao ;

Ling, Zongpeng ;

Wang, Yueyang ;

Dai, Huicong ;

Zhao, Zhenchao ;

Yang, Qihua .

CHEMCATCHEM, 2025, 17 (03)

[34] Enhanced Stability for Chemoselective Hydrogenation of Nitroarenes by Carbon Layer Coated Ni-Fe Alloy Catalyst [J].

Xie, Qingqing ;

He, Huizi ;

Qin, Xiaofei ;

Zhang, Min ;

Wan, Hongliu ;

Song, Chang ;

Yang, Yong ;

Sun, Xiaodong .

CHEMCATCHEM, 2023, 15 (12)

[35] Highly efficient and anti-poisoning single-atom cobalt catalyst for selective hydrogenation of nitroarenes [J].

Lin, Yuemin ;

Nie, Renfeng ;

Li, Yuting ;

Wu, Xun ;

Yu, Jiaqi ;

Xie, Shaohua ;

Shen, Yajing ;

Mao, Shanjun ;

Chen, Yuzhuo ;

Lu, Dan ;

Bao, Zongbi ;

Yang, Qiwei ;

Ren, Qilong ;

Yang, Yiwen ;

Liu, Fudong ;

Qi, Long ;

Huang, Wenyu ;

Zhang, Zhiguo .

NANO RESEARCH, 2022, 15 (12) :10006-10013

[36] Cobalt in N-doped carbon matrix catalyst for chemoselective hydrogenation of nitroarenes [J].

Dai, Yihu ;

Jiang, Chunyang ;

Xu, Min ;

Bian, Bo ;

Lu, Di ;

Yang, Yanhui .

APPLIED CATALYSIS A-GENERAL, 2019, 580 :158-166

[37] Studying the Three-Phase Hydrogenation of Nitrobenzene to Aniline in the Presence of a Ruthenium Catalyst [J].

Doluda, V. Yu ;

Filatova, A. E. ;

Sulman, E. M. ;

Matveeva, V. G. ;

Mikhailov, S. P. ;

Sidorov, A., I ;

Kosivtsov, Yu Yu .

CATALYSIS IN INDUSTRY, 2019, 11 (02) :147-153

[38] Ruthenium containing hydrotalcite as a heterogeneous catalyst for hydrogenation of benzene to cyclohexane [J].

Sharma, Sumeet K. ;

Sidhpuria, Kalpesh B. ;

Jasra, Raksh V. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 335 (1-2) :65-70

[39] Doped activated carbons obtained from nitrogen and sulfur-containing polymers as metal-free catalysts for application in nitroarenes hydrogenation [J].

Villora-Pico, Juan-Jose ;

Gil-Munoz, Gema ;

Sepulveda-Escribano, Antonio ;

Pastor-Blas, M. Mercedes .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 53 :490-502

[40] Pd immobilized on polymeric network containing imidazolium salt, cyclodextrin and carbon nanotubes: Efficient and recyclable catalyst for the hydrogenation of nitroarenes in aqueous media [J].

Sadjadi, Samahe ;

Koohestani, Fatemeh .

JOURNAL OF MOLECULAR LIQUIDS, 2020, 301

← 1 2 3 4 5 →