Robust Ruthenium Phosphide Catalyst for Hydrogenation of Sulfur- Containing Nitroarenes

被引:0
作者
Ishikawa, Hiroya [1 ]
Nakatani, Naoki [2 ]
Yamaguchi, Sho [1 ]
Mizugaki, Tomoo [1 ,3 ]
Mitsudome, Takato [1 ,4 ]
机构
[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan
[2] Tokyo Metropolitan Univ, Fac & Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan
[3] Osaka Univ, Inst Open & Transdisciplinary Res Initiat OTRI, Innovat Catalysis Sci Div, Suita, Osaka 5650871, Japan
[4] Japan Sci & Technol Agcy JST, PRESTO, Kawaguchi, Saitama 3330012, Japan
来源
ACS CATALYSIS | 2023年
关键词
hydrogenation; heterogeneous catalyst; phosphide; ruthenium; nitroarene; organosulfur compound; SELECTIVE HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; FUNCTIONALIZED NITROARENES; NITRO-COMPOUNDS; REDUCTION; NITROBENZENE; ADSORPTION; SURFACES; DESIGN;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Development of robust metal catalysts for the hydrogenation of sulfur-containing nitroarenes is challenging because the sulfur atom strongly poisons the active metal sites of the catalyst. We herein report that ruthenium phosphide nanoparticles (Ru2P/SiO2) act as a highly active and robust catalyst for the hydrogenation of sulfur-containing nitroarenes, with 34 times higher activity than that obtained with Ru nanoparticles. Various sulfurcontaining nitroarenes were hydrogenated under 1 bar of H2 and the corresponding anilines, including some important pharmaceutical intermediates, were obtained in high yields. The study results revealed that the electronic and geometrical effects of P surrounding Ru species in Ru2P/SiO2 are crucial to boost the activity and durability against sulfur poisoning.
引用
收藏
页码:5744 / 5751
页数:8
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