Encoding CsPbX3 perovskite quantum dots with different colors in molecularly imprinted polymers as fluorescent probes for the quantitative detection of Sudan I in food matrices

被引:23
作者
He, Jinxing [1 ]
Yu, Lu [1 ]
Jiang, Yandu [1 ]
Lu, Lei [1 ]
Han, Zhonghui [1 ]
Zhao, Xiaolei [1 ]
Xu, Zhixiang [2 ]
机构
[1] Qilu Univ Technol, Shandong Acad Sci, Sch Food Sci & Engn, Jinan 250353, Peoples R China
[2] Shandong Agr Univ, Coll Food Sci & Engn, Key Lab Food Proc Technol & Qual Control Shandong, Tai An 271018, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Sudan I; Perovskite quantum dots; Molecularly imprinted polymers; Encoded microspheres; Fluorescent probe; EFFICIENT; NANOCOMPOSITES; STABILITY;
D O I
10.1016/j.foodchem.2022.134499
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
All-inorganic cesium lead halides (CsPbX3, X = Cl, Br, I) perovskite quantum dots (PQDs) have attracted extensive research attention due to their unique optical properties. However, their instability and sensitivity to air and moisture hinder further use in fluorescent sensing applications. In this work, the construction and application of PQDs encoded molecularly imprinted polymers (MIPs-CsPbX3) for Sudan I detection were pro-posed. After being encoded the PQDs, the obtained MIPs-CsPbX3 microspheres exhibited high stability for the external environment, remarkable bright fluorescence, and specific recognition for Sudan I. The fluorescent intensity of the MIPs-CsPbX3 microspheres was obviously quenched upon loading Sudan I, and good linear re-sponses in the range of 0.5-150 mu g L-1, limit of detection of 0.3 mu g L-1, and good recoveries of 95.27 % to 105.96 % in spiked samples were obtained. The developed fluorescent probe provided a selective and sensitive quan-tified method for Sudan I detection in food matrices.
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页数:9
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