Synthesis and Optical Properties of Polyaryl 2-(Pyridin-2-yl)phenol-Based Four-Coordinate Organoboron Complexes

被引：13

作者：

Liu, Xiang ^{[1
,2
]}

Zhou, Jinlei ^{[1
,2
]}

Zheng, Huitao ^{[1
,2
]}

Liu, Jiali ^{[1
,2
]}

Liu, Zhihao ^{[1
,2
]}

Ni, Linying ^{[1
,2
]}

Kong, Xiangxi ^{[1
,2
]}

Zhang, Chen ^{[1
,2
,3
]}

Cao, Hua ^{[1
,2
]}

机构：

[1] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Zhongshan 528458, Guangdong, Peoples R China

[2] Guangdong Pharmaceut Univ, Guangdong Cosmet Engn & Technol Res Ctr, Zhongshan 528458, Guangdong, Peoples R China

[3] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510006, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2023年 / 41卷 / 08期

关键词：

N; O-Bidentate; Indolizines; Organoboron complexes; Cyclopropenones; C-N activation; N-Heterocycles; Cycloaddition; FLUORESCENT BF2 COMPLEXES; HYDROXYLATION; LIGAND; PHOTOOXYGENATION; INDOLIZINES; CATALYSIS;

D O I：

10.1002/cjoc.202200810

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of polyaryl 2-(pyridin-2-yl)phenol-based four-coordinate organoboron complexes were prepared in good yields via deconstructive cycloaromatization of indolizines, cyclopropenones, and boric acids. The photoluminescence measurements have revealed that these N,O pi-conjugated tetracoordinate boron complexes display bright fluorescence, large Stokes shifts, and good quantum yields (phi(lum) = 0.15-0.45). In addition, the DFT calculations were carried out to deepen the understanding of the electronic structures and optoelectronic properties of these structurally unprecedented tetracoordinate boron complexes.

引用

页码：924 / 930

页数：7

共 46 条

[31] Synthesis, crystal structures and luminescent properties of zinc(II) and cadmium(II) complexes with N,N-bis(pyridin-3-yl)-2,6-pyridinedicarboxamide [J].

Zhang, Fu-Li ;

Zhu, Yu ;

Zheng, Ju-Mei ;

Du, Chen-Xia ;

Wu, Yang-Jie .

JOURNAL OF MOLECULAR STRUCTURE, 2009, 928 (1-3) :108-113

[32] The Coordination chemistry and cyclic voltammetry exploration of Cu(II), Co(II), Ni(II) and Zn(II) complexes of novel (E)-3,4-dichloro-N-(2-(1-(pyridin-2-yl)ethylidene)hydrazine-1-carbonothioyl) benzamide ligand [J].

Al-Riyahee, Ali ;

Shenta, Ashwaq ;

Saud, Khansaa .

EGYPTIAN JOURNAL OF CHEMISTRY, 2021, 64 (11) :6337-6362

[33] Synthesis, X-ray structure and molecular properties of a new cobalt(III) complex of the type [Co(L)(SCN)2]ClO4 [L= N,N′-(bis(pyridin-2-yl)benzylidene)-1,2-ethanediamine] [J].

Chowdhury, Habibar ;

Paul, Indrani .

JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2017, 94 (03) :245-252

[34] Zinc(II) complexes derived from the di-Schiff-base ligand N,N′-bis[1(pyridin-2-yl)ethylidene]ethane-1,2-diamine (LA) and its hydrolytic-cleavage product N-[1-pyridin-2-yl)ethylidene]ethane-1,2-diamine (L):: preparation, characterization and crystal structure of the 5-coordinate species [ZnLCl2] [J].

Gourbatsis, S ;

Perlepes, SP ;

Butler, IS ;

Hadjiliadis, N .

POLYHEDRON, 1999, 18 (18) :2369-2375

[35] Di(pyridin-2-yl)amino-substituted 1,10-phenanthrolines and their Ru(<sc>ii</sc>)-Pd(<sc>ii</sc>) dinuclear complexes: synthesis, characterization and application in Cu-free Sonogashira reaction [J].

Ionova, Violetta A. ;

Dmitrieva, Alena V. ;

Abel, Anton S. ;

Sergeev, Aleksandr D. ;

Evko, Grigory S. ;

Yakushev, Alexei A. ;

Gontcharenko, Victoria E. ;

Nefedov, Sergei E. ;

Roznyatovsky, Vitaly A. ;

Cheprakov, Andrey V. ;

Averin, Alexei D. ;

Magdesieva, Tatiana V. ;

Beletskaya, Irina P. .

DALTON TRANSACTIONS, 2024, 53 (41) :17021-17035

[36] Eu(III) AND Tb(III) COMPLEXES BASED ON DIPHENYL(PYRIMIDIN-2-YL)PHOSPHINE OXIDE: SYNTHESIS, STRUCTURE, AND PHOTOLUMINESCENT PROPERTIES [J].

Bryleva, Yu. A. ;

Artem'ev, A. V. ;

Glinskaya, L. A. ;

Samsonenko, D. G. ;

Rakhmanova, M. I. ;

Davydova, M. P. ;

Yzhikova, K. M. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (02) :265-276

[37] Synthesis, cytotoxicity and DNA-binding properties of Pd(II), Cu(II) and Zn(II) complexes with 4′-(4-(2-(piperidin-1-yl)ethoxy)phenyl)-2,2′:6′,2"-terpyridine [J].

Chu, Wenhao ;

Wang, Yuechai ;

Liu, Siyuan ;

Yang, Xueyun ;

Wang, Shuxiang ;

Li, Shenghui ;

Zhou, Guoqiang ;

Qin, Xinying ;

Zhou, Chuanqi ;

Zhang, Jinchao .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2013, 23 (18) :5187-5191

[38] Synthesis, Crystal Structure and Magnetic Properties of Heteropolynuclear ReIVMII Complexes Based on the Robust [ReCl5(pyzCOO)]2- Unit (pyzCOO=2-pyrazinecarboxylate) [J].

Arizaga, Livia ;

Gonzalez, Ricardo ;

Armentano, Donatella ;

De Munno, Giovanni ;

Novak, Miguel A. ;

Lloret, Francesc ;

Julve, Miguel ;

Kremer, Carlos ;

Chiozzone, Raul .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (12) :1835-1845

[39] NEW COMPLEXES OF 2-(1H-1, 2, 4-TRIAZOL-3-YL) PYRIDINE WITH Co(II), Cd(II), Rh(III), IONS: SYNTHESIS, STRUCTURE, PROPERTIES AND POTENTIAL APPLICATIONS [J].

Horlescu, Petronela ;

Sutiman, Daniel ;

Stan, Corneliu S. ;

Mita, Carmen ;

Peptu, Cristian ;

Fortuna, Maria E. ;

Albu, Cristina .

ENVIRONMENTAL ENGINEERING AND MANAGEMENT JOURNAL, 2015, 14 (02) :389-397

[40] Novel 2D isomorphic lanthanide complexes based on a bifunctional 5-(pyridin-3-yloxy)isophthalic acid: synthesis, structure, fluorescence and magnetic properties [J].

Wei, Wenwen ;

Zhang, Xue ;

Lu, Liping ;

Feng, Sisi .

CRYSTENGCOMM, 2022, 24 (35) :6204-6214

← 1 2 3 4 5 →