Removal of heavy metals from polluted aqueous media using berry leaf

被引:7
作者
Mangood, Ahmed H. [1 ]
Abdelfattah, Ibrahim [2 ]
El-Saied, Fathy A. [1 ]
Mansour, Mostafa Z. [1 ]
机构
[1] Menoufia Univ, Fac Sci, Chem Dept, Shibin Al Kawm, Egypt
[2] Natl Res Ctr, Water Pollut Res Dept, Giza, Egypt
关键词
Adsorption; heavy metals; kinetic; optimum parameters; pseudo – second – order; wastewater; HEALTH-RISK ASSESSMENT; WASTE-WATER; ADSORPTION; BIOSORPTION; EQUILIBRIUM; BIOSORBENT; IONS; CD(II); ADSORBENT; CADMIUM;
D O I
10.1080/03067319.2021.1928102
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The routine of low-cost adsorbents derived from plant or agricultural by-products as a substitute for expensive traditional removal methods of heavy metal from discarded streams has been investigated. The effectiveness of powder's mulberry leaves in extracting Pb2+, Ni2+, Cu2+, and Co2+ from an aqueous solution by batch adsorption at lab ambient temperature (25 +/- 0.4 degrees C) was investigated in this report. The impact of pH, contact time, biosorbent dosage, and preliminary concentration of metal ions on the exclusion percentage were investigated in experiments. The findings demonstrated that the elimination of metal ions by mulberry leaves powder was influenced by all adsorption parameters. At pH = 6 and 7, the maximum removal of Ni2+, Pb2+, Cu2+, and Co2+ occurred. The obtained data were subjected to two different isotherm models Langmuir and Freundlich. The models of Pb2+, Ni2+, and Co2+ results all complement the Langmuir isotherm well (R-2 = 0.99). However, the Freundlich isotherm was found to match Cu2+ adsorption with (R-2 = 0.98). For Pb2+, Cu2+, Ni2+, and Co2+, the maximum monolayer adsorption potential was found to be 0.50, 2.88,1.14, and 1.15 mg/g, respectively. A sample of real industrial wastewater was collected and treated with mulberry leaf powder. The findings illustrate that mulberry leaves powder has a 69, 85, and 100% performance in removing Pb2+, Cu2+, Zn2+, ions, respectively. The findings of different treatments; synthetic and real wastewater, suggest that mulberry leaves powder may be applied as a low-cost alternative to more expensive heavy metal adsorbents. The pseudo-second-order kinetic model was applied to fit the model and describe the adsorption mechanism.
引用
收藏
页码:4450 / 4466
页数:17
相关论文
共 53 条
[1]  
Abdel Azzem, 2021, INT J ANALYTICAL CHE
[2]  
Abdelfattah Ibrahim, 2016, Environmental Nanotechnology, Monitoring and Management, V6, P176, DOI 10.1016/j.enmm.2016.10.007
[3]  
Abdelfattah I, 2016, RES J PHARM BIOL CHE, V7, P239
[4]  
Abdul, 2014, J IRANICA ENG ENV, V5, P446
[5]   Removal of lead(II) from wastewater by activated carbon developed from Tamarind wood by zinc chloride activation [J].
Acharya, Jyotikusum ;
Sahu, J. N. ;
Mohanty, C. R. ;
Meikap, B. C. .
CHEMICAL ENGINEERING JOURNAL, 2009, 149 (1-3) :249-262
[6]   Simultaneous removal of heavy-metal ions in wastewater samples using nano-alumina modified with 2,4-dinitrophenylhydrazine [J].
Afkhami, Abbas ;
Saber-Tehrani, Mohammad ;
Bagheri, Hasan .
JOURNAL OF HAZARDOUS MATERIALS, 2010, 181 (1-3) :836-844
[7]   Rapid removal of cobalt ion from aqueous solutions by almond green hull [J].
Ahmadpour, A. ;
Tahmasbi, M. ;
Bastami, T. Rohani ;
Besharati, J. Amel .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 166 (2-3) :925-930
[8]   Surveying the efficiency of Platanus orientalis bark as biosorbent for Ni and Cr(VI) removal from plating wastewater as a real sample [J].
Akar, Sheida ;
Lorestani, Bahareh ;
Sobhanardakani, Soheil ;
Cheraghi, Mehrdad ;
Moradi, Omid .
ENVIRONMENTAL MONITORING AND ASSESSMENT, 2019, 191 (06)
[9]   Biosorption of Hg2+, Cd2+, and Zn2+ by Ca-alginate and immobilized wood-rotting fungus Funalia trogii [J].
Arica, MY ;
Bayramoglu, G ;
Yilmaz, M ;
Bektas, S ;
Genç, Ö .
JOURNAL OF HAZARDOUS MATERIALS, 2004, 109 (1-3) :191-199
[10]   The use of Neem biomass for the biosorption of zinc from aqueous solutions [J].
Arshad, Mamoona ;
Zafar, Muhammad Nadeem ;
Younis, Sadaf ;
Nadeem, Raziya .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 157 (2-3) :534-540