Cross-linkable fluorene-based hole transporting materials for perovskite solar cells

被引：3
|
作者：
Kamarauskas, Egidijus [1 ]
Jegorove, Aiste [2 ]
Cepas, Romualdas J. [1 ]
Daskeviciute-Geguziene, Sarune [2 ]
Genevicius, Kristijonas [1 ]
Franckevicius, Marius [3 ]
Talaikis, Martynas [5 ]
Dobuzinskas, Rokas [1 ]
Scheler, Florian [4 ]
Sveinbjornsson, Kari [4 ]
Jankauskas, Vygintas [1 ]
Getautis, Vytautas [2 ]
机构：
[1] Vilnius Univ, Inst Chem Phys, Sauletekio Ave 9, LT-10222 Vilnius, Lithuania
[2] Kaunas Univ Technol, Dept Organ Chem, Radvilenu Pl 19, LT-50254 Kaunas, Lithuania
[3] Ctr Phys Sci & Technol, Dept Mol Cpd Phys, Sauletekio Ave 3, LT-10257 Vilnius, Lithuania
[4] Helmholtz Zentrum Berlin Mat & Energie GmbH, Solar Energy Div, D-12489 Berlin, Germany
[5] Ctr Phys Sci & Technol, Dept Organ Chem, Sauletekio Ave 3, LT-10257 Vilnius, Lithuania
来源：
CHEMICAL PHYSICS | 2024年 / 579卷
关键词：
Cross-linking; Hole transport material; Solar cells; Energetic and spatial disorder; SPIRO-OMETAD; EFFICIENT; POLYMER; STYRENE;
D O I：
10.1016/j.chemphys.2024.112183
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cross-linkable hole transporting materials (HTMs) based on fluorene core containing vinyl groups were synthesized and analyzed. It has been demonstrated that these HTMs are cross-linkable at temperatures above 200 degrees C and they are thermally stable at up to 400 degrees C. Cross-linking has little effect on energy level (HOMO) and causes only slight changes in the hole drift mobility values at room temperature, due to changes in spatial and energetic disorder. While employing cross-linked fluorene-diphenylamine derivative (<bold>V1145</bold>) as an HTM layer between perovskite and indium-tin oxide (ITO) in inverted perovskite solar cells (PSCs), the power conversion efficiency (PCE) of the cell was 11.42% (under AM 1.5G 100 mW cm(-2) illumination), demonstrating the potential of the presented class of dopant-free organic HTMs.
引用
收藏
页数：7
相关论文
共 50 条
  • [31] Graphdiyne-modified cross-linkable fullerene as an efficient electron-transporting layer in organometal halide perovskite solar cells
    Li, Meng
    Wang, Zhao-Kui
    Kang, Tin
    Yang, Yingguo
    Gao, Xingyu
    Hsu, Chain-Shu
    Li, Yuliang
    Liao, Liang-Sheng
    NANO ENERGY, 2018, 43 : 47 - 54
  • [32] Optical properties of cross-linkable fluorene copolymers
    Morgado, Jorge
    Charas, Ana
    Alves, Helena
    Alcacer, Luis
    Cacialli, Franco
    ORGANIC OPTOELECTRONICS AND PHOTONICS II, 2006, 6192
  • [33] New fluorene-based bipolar charge transporting materials
    Jegorove, Aiste
    Daskeviciene, Maryte
    Kantminiene, Kristina
    Jankauskas, Vygintas
    Cepas, Romualdas Jonas
    Gruodis, Alytis
    Getautis, Vytautas
    Genevicius, Kristijonas
    RSC ADVANCES, 2024, 14 (05) : 2975 - 2982
  • [34] Phosphorescent organic light emitting diodes with a cross-linkable hole transporting material
    Xiang, Chaoyu
    Chopra, Neetu
    Wang, Jing
    Brown, Christopher
    Ho, Szuheng
    Mathai, Mathew
    So, Franky
    ORGANIC ELECTRONICS, 2014, 15 (07) : 1702 - 1706
  • [35] A new binaphthol based hole-transporting materials for perovskite solar cells
    Zong, Xueping
    Qiao, Wenhua
    Chen, Yu
    Sun, Zhe
    Liang, Mao
    Xue, Song
    TETRAHEDRON, 2017, 73 (24) : 3398 - 3405
  • [36] Selenophene-Based Hole-Transporting Materials for Perovskite Solar Cells
    Illicachi, Luis A.
    Urieta-Mora, Javier
    Momblona, Cristina
    Molina-Ontoria, Agustin
    Calbo, Joaquin
    Arago, Juan
    Insuasty, Braulio
    Ortiz, Alejandro
    Orti, Enrique
    Martin, Nazario
    Nazeeruddin, Mohammad Khaja
    CHEMPLUSCHEM, 2021, 86 (07): : 1006 - 1013
  • [37] Perovskite Solar Cells Based on Oligotriarylamine Hexaarylbenzene as Hole-Transporting Materials
    Shasti, Mona
    Volker, Sebastian F.
    Collavini, Silvia
    Valero, Silvia
    Ruiperez, Fernando
    Mortezaali, Abdollah
    Zakeeruddin, Shaik M.
    Gratzel, M.
    Hagfeldt, A.
    Luis Delgado, Juan
    ORGANIC LETTERS, 2019, 21 (09) : 3261 - 3264
  • [38] Truxene-based Hole-transporting Materials for Perovskite Solar Cells
    Lin Lin-Lin
    Tu Yong-Guang
    Tang Chang-Quan
    Ma Yun-Long
    Chen Shan-Ci
    Yin Zhi-Gang
    Wei Jia-Jun
    Zheng Qing-Dong
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35 (10) : 1517 - 1524
  • [39] Truxene-based Hole-transporting Materials for Perovskite Solar Cells
    林琳琳
    涂用广
    汤昌泉
    马云龙
    陈善慈
    尹志刚
    魏佳骏
    郑庆东
    结构化学, 2016, 35 (10) : 1517 - 1524
  • [40] Emerging of Inorganic Hole Transporting Materials For Perovskite Solar Cells
    Rajeswari, Ramireddy
    Mrinalini, Madoori
    Prasanthkumar, Seelam
    Giribabu, Lingamallu
    CHEMICAL RECORD, 2017, 17 (07): : 681 - 699
12345