Synthesis and Characterization of the Trichlates [N(CH3)4][Cl3CSO3], [NH4][Cl3CSO3], and the Dichlate [NH4][Cl2CHSO3]

被引：2
|
作者：
Mertens, Alisha [1 ]
van Gerven, David [1 ]
Lee, Hyunsong [1 ]
Wickleder, Mathias S. [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, Greinstr 6, D-50939 Cologne, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2024年 / 27卷 / 04期
关键词：
Density functional calculations; dichloromethanesulfonate; IR spectroscopy; trichlate; trichloromethanesulfonate; X-ray diffraction; TRIFLUOROMETHANESULFONIC ACID; INFRARED-SPECTRA; ANIONS; SILVER; NQR;
D O I：
10.1002/ejic.202300535
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Trichlates are the rarely-described bigger siblings of the well-known triflates. The cation has been obtained in form the [NH4]+ and the [N(CH3)(4)]+ salt, respectively. Moreover, the dichlate anion, [Cl2CHSO3]- could be characterized for the first time. image
引用
收藏
页数：7
相关论文
共 50 条
  • [41] The synthesis and characterization of [4-CH3OC6H4CH2NH3]4P2O7•6H2O
    Selmi, A.
    Akriche, S.
    Rzaigui, M.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2006, 181 (09) : 2201 - 2211
  • [42] Structure and optical properties of amorphous AsS3-WS3 3-WS 3 thin films prepared by spin-coating using mixed n-propylamine-based solutions of AsS3 3 glass and (NH4)2WS4 4 ) 2 WS 4 powder
    Durcikova, Lenka
    Jancalek, Jiri
    Prikryl, Jan
    Mistrik, Jan
    Frumarova, Bozena
    Slang, Stanislav
    Provotorov, Pavel
    Kolobov, Alexander V.
    Krbal, Milos
    CERAMICS INTERNATIONAL, 2024, 50 (18) : 32233 - 32239
  • [43] Synthesis and characterization of a now p-phenylenediammonium dihydrogenmonophosphate [p-NH3C6H4NH3][H2PO4]2
    Mrad, M. L.
    Ben Nasr, C.
    Rzaigui, M.
    MATERIALS RESEARCH BULLETIN, 2006, 41 (07) : 1287 - 1294
  • [44] Synthesis and characterization of a new organic sulphate, [2,3-(CH3)2C6H3NH3]HSO4•H2O
    Sahbani, T.
    Smirani, W.
    Al-Deyab, Salem S.
    Rzaigui, M.
    MATERIALS RESEARCH BULLETIN, 2012, 47 (06) : 1455 - 1458
  • [45] Vibrational study of (CH3)4NSbCl6 and [(CH3)4N]2SiF6
    Ouasri, A
    Rhandour, A
    Dhamelincourt, MC
    Dhamelincourt, P
    Mazzah, A
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2002, 58 (12) : 2779 - 2788
  • [46] Preparation, Geometric and Electronic Structures of [Bi2Cu4(SPh)8(PPh3)4] with a Bi2 Dumbbell, [Bi4Ag3(SePh)6Cl3(PPh3)3]2 and [Bi4Ag3(SePh)6X3(PPhiPr2)3]2 (X =Cl, Br) with a Bi4 Unit
    Sommer, Heino
    Eichhoefer, Andreas
    Drebov, Nedko
    Ahlrichs, Reinhart
    Fenske, Dieter
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (32) : 5138 - 5145
  • [47] [Me4N15[WOS3(CuCl)3Cl]Cl2 -: a cluster compound with alternating anion packing
    Dilshad, R
    Boller, H
    Klepp, KO
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (13-14): : 2554 - 2557
  • [48] Advances in physicochemical characterization of lead-free hybrid perovskite [NH3(CH2)3NH3]CuBr4 crystals
    Lim, Ae Ran
    Kwac, Lee Ku
    SCIENTIFIC REPORTS, 2022, 12 (01)
  • [49] Synthesis, Structure, and Cyclic Voltammetric Property of Metal String Complex [Ni3(dpa)4(ClO4)(Cl)]•CH2Cl2
    Miao, Xiao-He
    Zhu, Long-Guan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (05): : 878 - 881
  • [50] Synthesis, chemical characterisation and molecular structure of [Ag3{μ3-Fe(CO)4}(dppm)3][NO3] and [Au3{μ-Fe(CO)4}(dppm)2][Cl]
    Albano, VG
    Castellari, C
    Iapalucci, MC
    Longoni, G
    Monari, M
    Paselli, A
    Zacchini, S
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 573 (1-2) : 261 - 266
12345