Synthesis and Characterization of the Trichlates [N(CH3)4][Cl3CSO3], [NH4][Cl3CSO3], and the Dichlate [NH4][Cl2CHSO3]

被引:2
|
作者
Mertens, Alisha [1 ]
van Gerven, David [1 ]
Lee, Hyunsong [1 ]
Wickleder, Mathias S. [1 ]
机构
[1] Univ Cologne, Inst Anorgan Chem, Greinstr 6, D-50939 Cologne, Germany
关键词
Density functional calculations; dichloromethanesulfonate; IR spectroscopy; trichlate; trichloromethanesulfonate; X-ray diffraction; TRIFLUOROMETHANESULFONIC ACID; INFRARED-SPECTRA; ANIONS; SILVER; NQR;
D O I
10.1002/ejic.202300535
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Trichlates are the rarely-described bigger siblings of the well-known triflates. The cation has been obtained in form the [NH4]+ and the [N(CH3)(4)]+ salt, respectively. Moreover, the dichlate anion, [Cl2CHSO3]- could be characterized for the first time. image
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页数:7
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