Synthesis and Characterization of the Trichlates [N(CH3)4][Cl3CSO3], [NH4][Cl3CSO3], and the Dichlate [NH4][Cl2CHSO3]

被引：2
|
作者：
Mertens, Alisha [1 ]
van Gerven, David [1 ]
Lee, Hyunsong [1 ]
Wickleder, Mathias S. [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, Greinstr 6, D-50939 Cologne, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2024年 / 27卷 / 04期
关键词：
Density functional calculations; dichloromethanesulfonate; IR spectroscopy; trichlate; trichloromethanesulfonate; X-ray diffraction; TRIFLUOROMETHANESULFONIC ACID; INFRARED-SPECTRA; ANIONS; SILVER; NQR;
D O I：
10.1002/ejic.202300535
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Trichlates are the rarely-described bigger siblings of the well-known triflates. The cation has been obtained in form the [NH4]+ and the [N(CH3)(4)]+ salt, respectively. Moreover, the dichlate anion, [Cl2CHSO3]- could be characterized for the first time. image
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Trichlates, an Unattended Class of Compounds: Characterization of Cl3CSO2Cl, and (H5O2)[Cl3CSO3]
    Mertens, Alisha
    van Gerven, David
    Kunert, Ilka
    Wickleder, Mathias S.
    CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (63)
  • [2] The reaction of NH4Cl with SO3: Two modifications of (NH4)[SO3Cl]
    Zimmermann, Vanessa
    Schindler, Lisa, V
    van Gerven, David
    Wickleder, Mathias S.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2022, 648 (24):
  • [3] The Molecular Structures of Lithium Trichlate, Li[Cl3CSO3]•2H2O, and Lithium Tribrate, Li[Br3CSO3]•2H2O
    Mertens, Alisha
    Eppers, Katrin
    van Gerven, David
    Wickleder, Mathias S.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2024, 27 (16)
  • [4] Crystal structure of Na3(NH4)2[Ir(SO3)2Cl4]•4H2O
    Baidina, I. A.
    Il'yashevich, V. D.
    Malakhov, V. F.
    Belyaev, A. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (05) : 973 - 976
  • [5] Crystal structure of Na3(NH4)2[Ir(SO3)2Cl4]·4H2O
    I. A. Baidina
    V. D. Il’yashevich
    V. F. Malakhov
    A. V. Belyaev
    Journal of Structural Chemistry, 2007, 48 : 973 - 976
  • [6] [(CH3C)(4)N-(CH3)(2)AL...CL...AL(CH3)(2)-N(CCH3)(4)]LI - AN UNUSUAL SANDWICH COMPLEX OF LITHIUM
    HAUSEN, HD
    TODTMANN, J
    WEIDLEIN, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 466 (1-2) : C1 - C4
  • [7] First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O
    M. A. Il’in
    V. A. Emel’yanov
    I. A. Baidina
    Journal of Structural Chemistry, 2010, 51 : 99 - 106
  • [8] Synthesis and characterization of a new chlorozincophosphate [H3N(CH2)2NH3]0.5Zn(HPO4)Cl
    Rayes, A
    Ben Nasr, C
    Rzaigui, M
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2005, 180 (01) : 41 - 52
  • [9] FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O
    Il'in, M. A.
    Emel'yanov, V. A.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 51 (01) : 99 - 106
  • [10] New Syntheses and Structural Characterization of NH3BH2Cl and (BH2NH2)3 and Thermal Decomposition Behavior of NH3BH2Cl
    Lingam, Hima K.
    Wang, Cong
    Gallucci, Judith C.
    Chen, Xuenian
    Shore, Sheldon G.
    INORGANIC CHEMISTRY, 2012, 51 (24) : 13430 - 13436
12345