Investigating the viscoelastic and hysteresis behavior of nano silica/carbon black hybrid reinforced styrene-butadiene rubber vulcanizates via surface silanization

被引:7
作者
Kalantari, Masoumeh [1 ]
Abdi, Roxana [2 ]
Katbab, Ali Asghar [1 ]
机构
[1] Amirkabir Univ Technol, Dept Polymer Engn & Color Technol, Tehran, Iran
[2] Azad Univ, Sci & Res Branch, Tehran, Iran
关键词
hysteresis; silica/carbon black hybrid; styrene-butadiene rubber (SBR); viscoelastic; CARBON-BLACK; INTERFACIAL INTERACTION; MECHANICAL-PROPERTIES; FILLER INTERACTIONS; NATURAL-RUBBER; POLYMER-FILLER; SILICA; SBR; COMPOSITES; FLOCCULATION;
D O I
10.1002/pen.26379
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
With the thought of green tires and the need of replacing carbon reinforcing fillers with noncarbon silica filler, the effectiveness of silane surface modification on dispersion state, dynamic viscoelastic, hysteresis, and abrasion resistance of SBR vulcanizates filled with a hybrid of carbon black (CB)/nano SiO2 is investigated. In situ surface modification of nano SiO2 is carried out using bis-(?-triethoxysilylpropyl)-tetrasulfide (TESPT), and various compounds with different ratios of CB/SiO2 are prepared via a melt mixing process in an internal bath mixer. Scanning electron microscopy (SEM) and FT-IR spectroscopy revealed improved dispersion of silica and CB clusters with enhanced molecular interactions using in situ surface modification with 5 phr of TESPT is performed. Evidence for enhanced molecular interactions included lower dynamic loss (tand) and less hysteresis measured via dynamic mechanical thermal analysis (DMTA). Our results indicate that appropriate modification of silica allows partial replacement of carbon black with silica for production of eco-friendly rubber products.
引用
收藏
页码:2309 / 2320
页数:12
相关论文
共 44 条
[11]   Reclaimed Rubber in Situ Grafted with Soybean Oil as a Novel Green Reactive Plasticizer in SBR/Silica Compounds [J].
Hassan, Adeel A. ;
Formela, Krzysztof ;
Wang, Shifeng .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (17) :14991-15001
[12]   Vulcanization kinetics of nano-silica filled styrene butadiene rubber [J].
Hosseini, Seyed Mostaffa ;
Razzaghi-Kashani, Mehdi .
POLYMER, 2014, 55 (24) :6426-6434
[13]   The role of reduced graphene oxide as a secondary filler in improving the performance of silica-filled styrene-butadiene rubber compounds [J].
Kalat, Mana Nabavian ;
Razzaghi-Kashani, Mehdi .
POLYMER JOURNAL, 2022, 54 (03) :355-365
[14]   Vulcanizate Structures of SBR Compounds with Silica and Carbon Black Binary Filler Systems at Different Curing Temperatures [J].
Kim, Il Jin ;
Kim, Donghyuk ;
Ahn, Byungkyu ;
Lee, Hyung Jae ;
Kim, Hak Joo ;
Kim, Wonho .
POLYMERS, 2020, 12 (10) :1-15
[15]   Synthesis of novel functional liquid and its application as a modifier in SBR/silica composites [J].
Lei, Y. D. ;
Tang, Z. H. ;
Guo, B. C. ;
Zhu, L. X. ;
Jia, D. M. .
EXPRESS POLYMER LETTERS, 2010, 4 (11) :692-703
[16]   Enhanced Mechanical and Processing Property of Styrene-butadiene Rubber Composites with Novel Silica-supported Reactive Processing Additive [J].
Li, Simin ;
Luo, Yuanfang ;
Chen Yongjun ;
Xu, Tiwen ;
Zhong, Bangchao ;
Jia, Zhixin ;
Jia, Demin .
FIBERS AND POLYMERS, 2019, 20 (08) :1696-1704
[17]   Rubber abrasion at steady state [J].
Liang, H. ;
Fukahori, Y. ;
Thomas, A. G. ;
Busfield, J. J. C. .
WEAR, 2009, 266 (1-2) :288-296
[18]   On the filler flocculation in silica-filled rubbers part I.: Quantifying and tracking the filler flocculation and polymer-filler interactions in the unvulcanized rubber compounds [J].
Lin, CJ ;
Hergenrother, WL ;
Alexanian, E ;
Böhm, GGA .
RUBBER CHEMISTRY AND TECHNOLOGY, 2002, 75 (05) :865-890
[19]   Insight into the effect of CB loading on tension, compression, hardness and abrasion properties of SBR and NBR filled compounds [J].
Mostafa, A. ;
Abouel-Kasem, A. ;
Bayoumi, M. R. ;
El-Sebaie, M. G. .
MATERIALS & DESIGN, 2009, 30 (05) :1785-1791
[20]   The role of cellulose nanowhiskers in controlling phase segregation, crystallization and thermal stimuli responsiveness in PCL-PEGx-PCL block copolymer-based PU for human tissue engineering applications [J].
Noormohammadi, Fatemeh ;
Nourany, Mohammad ;
Sadeghi, Gity Mir Mohamad ;
Wang, Peng-Yuan ;
Shahsavarani, Hosein .
CARBOHYDRATE POLYMERS, 2021, 252